A new ligand containing long alkyl (octadecyl) chains was used to obtain the mesogenic complex [L2Cu4(mu4-O)(OAc)4].EtOH (1). This complex was thoroughly characterized and had its molecular structure solved by X-ray diffraction (XRD). Mesomorphic properties were demonstrated by means of polarized microscopy, differential scanning calorimetry, and XRD.

The present study deals with the elastic analysis of concave thickness rotating disks made of functionally graded materials (FGMs).The analysis is carried out using element based gradation of material properties in radial direction over the discretized domain. The resulting deformation and stresses are evaluated for free-free boundary condition and the effect of grading index on the deformation...

background and objectives: antibacterial susceptibility testing of clinical bacterial isolates through disk diffusion method plays a major role in antibacterial treatment. one of the main factors affecting the result of these tests is the type, structure and quality of the disks. the main objective of this study was to compare the agreement of antibiotic disks originated from three companies on...

Poly(octadecyl acrylate) with a terminal reactive group was synthesized by radical telomerization in various solvents. The polymers were grafted onto porous silica for use in RP-HPLC, and the molecular recognition ability was investigated along with the selectivity for the structural isomers of polycyclic aromatic hydrocarbons. The mechanism of selectivity was also investigated with differentia...

The bis-complexes [Cu(L(dt))(2)](OTf)(2) (1) and [Cu(L(ot))(2)](OTf)(2) (2), where L(dt) = 1-dodecyl-1,4,7-triazacyclononane, L(ot) = 1-octadecyl-1,4,7-triazacyclononane and OTf = trifluoromethanesulfonate, formed a novel class of metallo-liposomes in water that transfect pEGFP-N1 plasmids into HEK 293-T cells at 38% and 4% efficiency, respectively.

A new and facile assay for hydroxyl radicals in photocatalytic systems is reported for the first time that is based on the fluorescence imaging of increasing hydrophilic regions through the highly selective hydroxyl radical-induced lateral remote oxidation of superhydrophobic 1-octadecanethiol molecules at gold flower-like surface in the designed photomask setup.