ordered mesoporous carbon cmk-3 (omc) have been synthesized using mesoporous sba-15 silica as template and modified with cobalt carbonate. morphologies and surface texturing of materials werecharacterized by x-ray diffraction (xrd), scanning electron microscopy (sem) and n2 adsorption-desorptionisotherms. the cobalt modified ordered mesoporous carbon were found to have a surface area of 490.06m...

Large-dimension heterogeneous nanoporous membranes were obtained by the formation of CdS doped mesoporous silica within the porous channels of alumina membranes.

Although surfaces or, more precisely, the surface atomic and electronic structure, determine the way materials interact with their environment, the influence of surface chemistry on the bulk of the material is generally considered to be small. However, in the case of high surface area materials such as nanoporous solids, surface properties can start to dominate the overall material behavior. Th...

Using liquid crystalline self-assembly of cellulose nanocrystals, we achieve long-range alignment of anisotropic metal nanoparticles in colloidal nanocrystal dispersions that are then used to deposit thin structured films with ordering features highly dependent on the deposition method. These hybrid films are comprised of gold nanorods unidirectionally aligned in a matrix that can be made of or...

A combination of a "top-down" approach (substrate-conformal imprint lithography) and two "bottom-up" approaches (dewetting and dealloying) enables fabrication of perfectly ordered 2-dimensional arrays of nanoporous gold nanoparticles. The dewetting of Au/Ag bilayers on the periodically prepatterned substrates leads to the interdiffusion of Au and Ag and the formation of an array of Au-Ag alloy ...

Prototyping of nanoporous carbon membranes with three-dimensional microscale patterns is significant for integration of such multifunctional materials into various miniaturized systems. Incorporating nano material synthesis into microelectronics technology, we present a novel approach to direct prototyping of carbon membranes with highly nanoporous structures inside. Membranes with significant ...

Supercapacitors are electrochemical energy-storage devices that exploit the electrostatic interaction between high-surface-area nanoporous electrodes and electrolyte ions. Insight into the molecular mechanisms at work inside supercapacitor carbon electrodes is obtained with (13)C and (11)B ex situ magic-angle spinning nuclear magnetic resonance (MAS-NMR). In activated carbons soaked with an ele...

Hierarchical nanoporous carbon (NPC) with great surface area and developed pore size distribution has been intently concerned. Herein, we report a facile method coupling template nanocasting and self-activation to fabricate nanoporous carbon with continuous micro, meso and macro pores, in which CaCO3 acted as template and activation reagent while the flour was the carbon precursor. Effects of m...

Realizing the vast technological potential of patternable block copolymers requires both the precise controlling of the orientation and long-range ordering, which is still a challenging topic so far. Recently, we have demonstrated that ordered nanoporous thin film can be fabricated from a simple supramolecular assembly approach. Here we will extend this approach and provide a general route to f...

Nanoporous carbon is coated by pure nickel via an electroless plating method. The nanoporous carbon provides a high-surface-area substrate, leading to a large capacitance; the nickel surface layer is of a high work function, resulting in a thermally sensitive electrode potential. Such a system is ideal for thermally chargeable supercapacitor (TCS) system, which converts low-grade heat (LGH) to ...