Understanding the hydrogen peroxide electrochemistry on platinum can provide information about the oxygen reduction reaction mechanism, whether H(2)O(2) participates as an intermediate or not. The H(2)O(2) oxidation and reduction reaction on polycrystalline platinum is a diffusion-limited reaction in 0.1 M HClO(4). The applied potential determines the Pt surface state, which is then decisive fo...

abstract aims: the application of photocatalytic processes to remove heavy metals in aqueous solutions and industrial wastewater are regarded as extremely effective, clean and without producing waste methods. the goal of the present study was to investigate the photocatalytic activity of zno based on h-zsm-5 zeolite support. materials & methods: zno/h-zsm-5 composite synthesized by impregnation...

A purified and electrophoretically homogeneous blue laccase from the litter-decaying basidiomycete Stropharia rugosoannulata with a molecular mass of approximately 66 kDa oxidized Mn to Mn , as assessed in the presence of the Mn chelators oxalate, malonate, and pyrophosphate. At rate-saturating concentrations (100 mM) of these chelators and at pH 5.0, Mn complexes were produced at 0.15, 0.05, a...

Observations from a number of different experimental approaches have implicated cytochrome pigments in oxidation-reduction reactions resulting from the illumination of photosynthetic tissues (l-6). Possible relationships of these cytochromes to those of the respiratory chain pigments which react with oxygen in the dark have been considered. Vernon (7) isolated a soluble cytochrome in good yield...

A purified and electrophoretically homogeneous blue laccase from the litter-decaying basidiomycete Stropharia rugosoannulata with a molecular mass of approximately 66 kDa oxidized Mn(2+) to Mn(3+), as assessed in the presence of the Mn chelators oxalate, malonate, and pyrophosphate. At rate-saturating concentrations (100 mM) of these chelators and at pH 5.0, Mn(3+) complexes were produced at 0....

The model has been developed by considering two distinct zones in the downdraft gasifier: pyro-oxidation zone and reduction zone. The process in the pyro-oxidation zone has been solved based on the chemical equilibrium consideration considering water gas shift reaction and methanation reaction. The composition of different species (H2, CO, CO2, CH4, H2O, N2 and Char) and the temperature of the ...

The present approach for determining the electrophilicity (E) and nucleophilicity (N) of aldehydes includes a kinetic study of KMNO4 oxidation and NaBH4 reduction of aldehydes. A transition state analysis of the KMNO4 promoted aldehyde oxidation reaction has been performed, which shows a very good correlation with experimental results. The validity of the experimental method has been tested usi...

Geological carbon sequestration captures CO2 from industrial sources and stores the CO2 in subsurface reservoirs, a viable strategy for mitigating global climate change. In assessing the environmental impact of the strategy, a key question is how microbial reactions respond to the elevated CO2 concentration. This study uses biogeochemical modeling to explore the influence of CO2 on the thermody...

HKUST-1, a copper-based metal organic framework (MOF), has been investigated as a catalyst in various reactions. However, the HKUST-1 shows low catalytic activity in the oxidation of catechol. Therefore, we synthesized Fe₃O₄@HKUST-1 by layer-by layer assembly strategy and Cu@Cu₂O by reduction of HKUST-1 for enhancement of catalytic activity. Cu@Cu₂O nanoparticles exhibited highly effective cata...

Rate data for electrochemical and homogeneous redox reactions involving R u , ~ + / ~ + , V,q3+/2+, Fe,q3+/2+, E u , ~ ~ + / ~ + , and Cr,2+/2+ redox couples (where "aq" represents aquo ligands) have been analyzed and compared by using the rate relations due to Marcus in order to ascertain how the kinetics of outer-sphere electron exchange are dependent upon the metal redox center. The work-cor...