The electronic density of states on Cu and Pd sites in Cu-Pd substitutlonal alloys has been investigated by soft x-ray emission spectroscopy and SCF-KKRCPA calculations. The results indicate that Cu-Pd can be described as a common band alloy with no Pd virtual bound state. Possible origins for the larger theoretical Pd bandwidth with respect to the experimental one are discussed. In a recent pa...

We present experimental and theoretical studies of Pd/Cu(100) and Cu/Pd(100) heterostructures in order to explore their structure and misfit strain relaxation. Ultrathin Pd and Cu films are grown by pulsed laser deposition at room temperature. For Pd/Cu, compressive strain is released by networks of misfit dislocations running in the [100] and [010] directions, which appear after a few monolaye...

Nano-sized nickel oxide (nano-NiO) is a new nanomaterial that has shown great promise in many areas of application. Understanding its environmental fate and effects is critical for minimizing the potential environmental implications of this new material due to incidental and accidental releases in the future. In this study, we observed strong adsorption of tetracycline to nano-NiO and found tha...

Highly stable monodispersed nano Cu hydrosols were facilely prepared by an aqueous chemical reduction method through selecting copper hydroxide (Cu(OH)2) as the copper precursor, poly(acrylic acid) (PAA) and ethanol amine (EA) as the complexing agents, and hydrazine hydrate as the reducing agent. The size of the obtained Cu colloidal nanoparticles was controlled from 0.96 to 26.26 nm by adjusti...

A Pd/Sn bimetallic nanoparticles resin (nano-Pd/Sn/resin) was successfully synthesized for reductive transformation of aqueous trichloroethylene (TCE). The physicochemical properties of the prepared resin were characterized using scanning electron microscopy, energy dispersive X-ray spectroscopy, N(2) isothermal sorption at and X-ray photospectroscopy. The surface-area-normalized rate constants...

Mixed-potential-driven catalysis could be a novel strategy to control catalytic selectivity. In this mechanism, anodic and cathodic reactions occur simultaneously, forming mixed potential on the nano-anode nano-cathode composed of supported catalyst. To prove mixed-potential-driven catalysis, we developed new model reactor with separated electrodes directly measure currents between under high-p...

Nano-sized ceramic particle reinforced aluminum composites exhibit excellent room-temperature mechanical properties. However, there is limited research on the dry sliding wear behavior of those composites at elevated temperatures, which should be one of the major concerns on elevated temperature applications. Here the Al-Cu composites reinforced with nano-sized TiCp were fabricated. The dry sli...

CuO nano particles were obtained by calcination of nano-sized  [Cu(C4H4O4)(bipy)(H2O)2].2H2O (1) and [Cu(2‚2′-bipy)](C4H4O4)0.5(NO3)(H2O) (2) which are two  Cu(II) coordination polymers. The two coordination polymers [Cu(C4H4O4)(bipy)(H2O)2].2H2O and [Cu(2‚2′-bipy)](C4H4O4)0.5(NO3)(H2O) were synthesized and characterized by Fourier transform infrared spectra (FT-IR spectroscopy), thermal gravim...

Experimental results obtained for Pd/PdO/ZrO2 nano-composite samples are summarized and the underlying physics is discussed. Arata-Zhang’s May 2008 excess heat result was replicated quantitatively. Using Pd/PdO/ZrO2 powders (produced by Santoku Co., Kobe Japan), we obtained: 1) D-gas charge in the first phase (zero pressure interval) gave 20~90% excess heat than H-gas charge. 2) In the second p...

Recently introduced micronized copper (MC) formulations, consisting of a nanosized fraction of basic copper (Cu) carbonate (CuCO3·Cu(OH)2) nanoparticles (NPs), were introduced to the market for wood protection. Cu NPs may presumably be more effective against wood-destroying fungi than bulk or ionic Cu compounds. In particular, Cu- tolerant wood-destroying fungi may not recognize NPs, which may ...