High pressure vapor-liquid equilibrium (VLE) of CO2-expanded organic solvents is investigated using Peng-Robinson-LCVM-UNIFAC equation of state. Bubble pressure of ten ternary mixtures is predicted using this mixing rule and correlations are developed based only on binary experimental data. Due to the lack of experimental data for liquid phase density in the literature, it was necessary to perf...

A PDAE model of a multicomponent gas pipeline has been formulated and solved using the ode15s solver of Matlab. The model with boundary conditions allows for reactions and di usion. Also, general cubic equations of state for pressure and enthalpy are described. To simplify the implementation at this stage, a non-reactive, non-di usional model with fixed feed composition is considered, and multi...

Abstract Phase equilibrium data ( $$p$$ p , $$T$$ T $$y$$ y ) for the binary systems of carbon dioxide + dimethyl carbonate and ethyl methyl were obtained. All measured isotherms ranging from 298.2 K to 328.2 with pressure between 0.13 MPa 10.6 MPa. A static technique was est...

Abstract The accurate calculations of adsorption equilibrium for multicomponent gas systems are of great importance in many applications. In this paper, five two-dimensional equations of state 2D-EOS, i.e. Van der Waals, Eyring, Zhou-Ghasem-Robinson, Soave-Redlich-Kwong and Peng-Robinson, were examined to find out their abilities to predict adsorption equilibrium for pure and multi-component ga...

The critical properties of a solute are required for modeling of the solubility by the equation of state. For many compounds, the critical properties are not available. So, group contribution method is utilized as a common method to estimate these properties. But, it leads to the consecutive errors in calculations of the solubility modeling. In this study, Soave-Redlish-Kowang (SRK) and Peng-Ro...

For some of the EOS models the dimension of equilibrium problem can be reduced. Stability and difficulties in implementation are among the problems of flash calculation. In this work, a new reduction technique is presented to prepare a reduced number of equilibrium equations. Afterwards, a number of appropriate solution variables are selected for the prepared equation system to solve the equati...