Pervaporation (PV) has shown great potential in the separation of butanol aqueous solutions due to their economic and environmental benefits. This work applies polydimethylsiloxane (PDMS) composite membrane separate four isomers (n-butanol, isobutanol, sec-butanol tert-butanol) solution. Based on physical chemical properties isomers, such as solubility, polarity interaction parameter, we system...

In this article, the pervaporation selectivity as a function of the membrane thickness is studied for the dehydration of acetic acid. From this study, it appeared that the selectivity of polysulfone (PSF) , poly (vinyl chloride) (PVC ) , and polyacrylonitrile (PAN) decreases with decreasing membrane thickness, below a limiting value of about 15 pm. However, in the case of gas separation, the se...

Dense flat-sheet membranes were prepared from poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) using the casting solvents chloroform and 1,1,2-trichloroethylene. X-ray diffraction, tapping mode atomic force microscopy (TM-AFM), and contact angle studies were used to characterize the membranes. The surface energy and the solubility parameters of the PPO membranes were determined from the measured co...

Increasing the hydrophobicity of membrane was believed as an effective approach to enhance the performance of organophilic pervaporation (PV) membrane. In this work, the superhydrophobic alkyl group modificated metal organic framework (MOF) of RHO-[Zn(eim)2] (MAF-6) was incorporated into polydimethylsiloxane (PDMS) polymer to fabricate mixed matrix membranes (MMMs). The morphologies, physical a...

A fast, clean and easy to automate flow injection-pervaporation method for the determination of ethanol in different beverages using density measurements is proposed. The method is based on separation of the ethanol from the sample using a pervaporation module; the analyte being collected in water as acceptor liquid. The density of this water-alcohol mixture is measured at the detector. After o...

The objectives of the present study were to recover and identify volatiles organic compounds (VOCs) in the wastewater (WW) coming from a soluble coffee industrial plant. For VOCs recover, the WW was concentrated by pervaporation using a polydimethylsiloxane (PDMS) membrane. Furthermore, the solid phase micro extraction (SPME) and gas chromatography-mass spectrometry (GC-MS) were used for VOCs i...

Pervaporation removal of methyl tert-butyl ether (MTBE) from dilute aqueous solutions was demonstrated using ceramic-supported polymer (CSP) membranes. These membranes were created by the free radical graft polymerization of vinyl acetate onto a vinyl trimethoxysilaneactivated porous silica substrate having a native average pore size of 500 Å. The resulting membranes consisted of poly(vinyl ace...

We use pervaporation-based microfluidic devices to concentrate species in aqueous solutions with spatial and temporal control of the process. Using experiments and modeling, we quantitatively describe the advection-diffusion behavior of the concentration field of various solutions (electrolytes, colloids, etc.) and demonstrate the potential of these devices as universal tools for the kinetic ex...

Pervaporation is a membrane process that offers high separation performance and has an important potential for the treatment of saline water sources. In this study, poly(vinyl alcohol) (PVA) PVA-SiO2 nanocomposite membranes were prepared by solution-casting method, pervaporative desalination studies carried out synthetic seawater (35 g L-1) at 30, 40 50?C. Effects temperatures incorporation SiO...