A summary of photo- and electrochemical surface modifications applied on single-crystalline chemical vapour deposition diamond films is given. The covalently bonded formation of amine and phenyl linker molecular layers is characterized using X-ray photoelectron spectroscopy, atomic force microscopy (AFM), cyclic voltammetry and field-effect transistor characterization experiments. Amine and phe...

A (1) (TS) J F,H(O) coupling pathway, dictated by a hydrogen bond, in some 2-fluorobenzoic acids has been observed, while such an interaction does not occur in 2-fluorophenol. Thus, this work reports the conformational analysis of 2-fluorophenylboronic acid (1), in order to evaluate a possible intramolecular OH∙∙∙F hydrogen bond in comparison to an nF→pB interaction, which mimics the quantum nF...

Isolated five known iridoids glycosides (Scrophuloside A, Harpagoside B, 5-hydroxyloganin, 8-O-acetylharpagide and 6-O-methyl,1-glucopyranosyl catalpol ),one phenyl ethanoid glycoside (Verbascoside) and a phenyl ethanol amine (2-(4-Chlorobenzyl amino) ethanol ) compound from the methanolic extract of aerial parts of Scrophularia oxysepala using by high performance liquid chromatography based on...

The synthesis and the solution/solid-state fluorescence properties of pyrimidine-based monoboron complexes differing in terms of the substituents [either two fluorine atoms (BF2 complex) or two phenyl groups (BPh2 complex)] on the boron atom are reported herein. Unrestricted C-Ar intramolecular rotation in the non-, trifluoromethyl-, and cyano-substituted derivatives resulted in negligible fluo...

boron toxicity usually occurs in arid and saline soils. among all the pollutant'sresource, irrigation water is the most important factor in boron elevating in the soil.modification of boron-rich soils is difficult and in this case, resistant varieties can playan important role in increasing the cultivation in areas with high boron level. to assessthe effects of different concentrations of ...

The electron-deficient pentaarylborole 1-(2',4',6'-tris(trifluoromethyl)phenyl)-2,3,4,5-tetraphenylborole (1) has been synthesised with the long-term aim of developing borole-based optoelectronic materials. The bulky 2,4,6-tris(trifluoromethyl)phenyl (FMes) group on the boron atom of 1 significantly improves (>600 times) its air stability relative to its mesityl analogue. Moreover, 1 shows good...

BACKGROUND Azaheterocycles are an important class of compounds because of their highly potent medicinal activities, and the imidazole subcategory is of special interest in regard to drug discovery research. FINDINGS An expeditious synthetic protocol of 2-aryl-4-phenyl-1H-imidazoles has been accomplished by reacting phenylglyoxal monohydrate, ammonium acetate, and aldehyde under sonication. Fo...

E rhard U hlem ann*, Alwin Friedrich, G erald Hinsche, W ulfhard Mickler, Uwe Schilde Institut für Anorganische Chemie und Didaktik der Chemie. Universität Potsdam, Postfach 601553, D-14415 Potsdam Z. Naturforsch. 50b, 37-42 (1995); eingegangen am 11. Juli 1994 3-Phenyl-4-benzoyl-5-isoxazolone, Crystal Structure, Thermal Stability, Complex Stability Constants, Dioxane/Water-Mixtures Acid consta...

Isolated five known iridoids glycosides (Scrophuloside A, Harpagoside B, 5-hydroxyloganin, 8-O-acetylharpagide and 6-O-methyl,1-glucopyranosyl catalpol ),one phenyl ethanoid glycoside (Verbascoside) and a phenyl ethanol amine (2-(4-Chlorobenzyl amino) ethanol ) compound from the methanolic extract of aerial parts of Scrophularia oxysepala using by high performance liquid chromatography based on...