Bathorhodopsin-rhodopsin difference spectra of native 11-cis-rhodopsin and regenerated 9-cis-rhodopsin were measured at room temperature with a double-beam laser spectrophotometer after excitation at 532 nm. A detailed analysis of data obtained at 85 psec after excitation suggests that the bathorhodopsins generated from 11-cis- and 9-cis-rhodopsin differ in their extinction coefficients and tha...

mesoporous tio2 has been prepared using a nonionic block copolymer (pluronic p-123) as structure-directing agent with sol-gel method. characterization of the product was carried out by means of x-ray diffraction (xrd), scanning electron microscopy (sem), thermogravimetry-differential scanning calorimetry (tg-dsc), nitrogen sorption isotherms, and uv-vis absorption spectroscopy. these analyses s...

In this paper, the photochemical degradation of azure-b by Cu2+/S2O82− process has beenpresented. Cu2+ as photocatalyst and S2O82− ion as photooxidant used in this process. Atextremely low concentrations, cupric ion showed true catalytic activity in the overall process.The influence of various parameters on the performance of the treatment process has beenconsidered, such as pH, concentration o...

Photochemical reactions of microcystin-LR, a toxic compound produced by some blue green algae, were investigated. Ultraviolet absorption of microcystin-LR was assessed. Time-dependent density functional theory (TDDFT) calculations indicated that absorption peak at 238 nm was mainly due to excitation of electrons from the linear chain structure Adda of microcystin-LR. Irradiation of microcystin-...

[1] We develop a 1-D steady state photochemical model of the modern Martian atmosphere and apply it to possible Martian atmospheres present and past. A unique feature of our model is that the major current sink of oxygen is dry deposition (surface reactions) of highly reactive, oxidized molecules (chiefly H2O2), rather than oxygen escape to space. Another difference is that we allow hydrogen to...

To provide further evidence that the multiple cerebral infarcts found in rats following photochemical damage to the carotid artery are caused by emboli and to eliminate the systemic hypotension and heating of the blood reported with the previous photochemical embolic stroke model (rose bengal and a green laser), I have modified the photochemical technique. Brain pathology was studied in 18 Wist...

PURPOSE Photochemical internalization is under development for improving macromolecular therapy by inducing photochemical damage to endocytic vesicles. This damage leads to the release of therapeutic macromolecules entrapped in endocytic vesicles into the cytosol. The macromolecules may in this way be able to interact with therapeutic targets instead of being degraded by lysosomal hydrolases. B...

the resource intensive human activities (such as mining and extraction of mineral oils for betterment of life and modernization of society) have increased environmental pollution several folds. products of mining and petrochemical industries are advantageous for the modern society. but waste generated such as btex from such industries are carcinogenic, toxic and causes adverse effects on enviro...

When a nematic liquid crystal is doped with a large amount of a liquid crystalline azobenzene compound (15 wt %), the photoisomerization of azobenzene under UV and visible light irradiation can give rise to reversible and interconvertible photochemical phase transition and photochemical phase separation. Both normal and reverse modes of photocontrolled switching of transmittance through crossed...