A heuristic model based on dielectric continuum theory for the long-range solvation free energy of a dipolar system possessing periodic boundary conditions (PBCs) is presented. The predictions of the model are compared to simulation results for Stockmayer fluids simulated using three different cell geometries. The boundary effects induced by the PBCs are shown to lead to anisotropies in the app...

We present a Ginzburg-Landau theory of ion-induced nucleation in a gas phase of polar one-component fluids, where a liquid droplet grows with an ion at its center. By calculating the density profile around an ion, we show that the solvation free energy is larger in gas than in liquid at the same temperature on the coexistence curve. This difference much reduces the nucleation barrier in a metas...

We present a method to search low energy configurations of polar molecules in the complex potential energy surfaces associated with dense fluids. The search is done in the configurational space of the translational and rotational degrees of freedom of the molecule, combining steepest-descent and Newton-Raphson steps which embed information on the average sizes of the potential energy wells obta...

We investigated the relations between the yield stress of polar-molecule dominated electrorheological (PM-ER) fluids and the shape of ellipsoidal particles of the fluids. It is found that, when the short axis of an ellipsoidal particle is along an external electric field while the volume of the particle keeps constant, the shorter of the short axis is, the stronger the attraction between the tw...

Using the 3+1 formalism of general relativity we obtain the equations governing the dynamics of spherically symmetric spacetimes with arbitrary sources. We then specialize for the case of perfect fluids accompanied by a flow of interacting massless or massive particles (e.g. neutrinos) which are described in terms of relativistic transport theory. We focus in three types of coordinates: 1) isot...

Ionic liquids (ILs) are finding technological applications as chemical reaction media and engineering fluids. Some emerging fields are those of lubrication, surface engineering and nanotechnology. ILs are thermally stable, non-flammable highly polar fluids with negligible volatility, these characteristics make them ideal candidates for new lubricants under severe conditions, were conventional o...

A variety of simple bent-core molecules exhibit smectic liquid crystal phases of planar fluid layers that are spontaneously both polar and chiral in the absence of crystalline order. We found that because of intralayer structural mismatch, such layers are also only marginally stable against spontaneous saddle splay deformation, which is incompatible with long-range order. This results in macros...

Micropolar fluids are with microstructure and belong to a class of asymmetric stress tensor that called Polar fluids, include, as special case, the well-established Navier–Stokes model. In this work we study 3D micropolar model Navier boundary conditions without friction for velocity field homogeneous Dirichlet angular velocity. Using Galerkin method, prove existence weak solutions establish Pr...

Nematic fluids with polar order could be most useful new molecular materials. However, such ferroelectric liquid crystals have not been observed as yet. This paper describes the first computer simulations of a ferroelectric nematic phase made from simple tapered particles as shown in the picture and gives some hints about the relevant molecular features.

With high pressures, supercritical fluids can be studied over a very wide range of density. Fluids with strongly interacting polar molecules for example water are of particular interest. Results for several thermophysical properties are discussed. Density, dielectric constant and self—ionization of water have been determined or predicted to 1000 °C. Beyond 20 GPa very hot water appears to becom...