Highly dense arrays of ordered and aligned nanorods of polyaniline with 10 nm diameter on transparent ITO substrate have been successfully fabricated using supramolecular assemblies of block copolymer as scaffold material; the ordered arrays of polyaniline nanorods so fabricated were found to exhibit excellent electrochemical properties with an electrochemical capacitance value of 3407 F g(-1).

the direct synthesis of polyaniline-tio2 nanocomposite coatings on aluminum alloy 3004 (aa3004) surface has been investigated by using the galvanostatic method. the synthesized coatings were characterized by ft-ir, sem-edx, sem and afm. optical absorption spectroscopy reveals the formation of the emeraldine oxidation state form of polyaniline-tio2 nanocomposite. the corrosion performances of po...

This study aims at exploring an effective route in the in situ graft polymerization of aniline from Fe3O4 nanoparticles. To this goal, Fe3O4 magnetic nanoparticles were prepared by coprecipitation method using ammonia solution as the precipitating agent, and were characterized by Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD) and transmission electron microscopy (TEM)....

The direct synthesis of polyaniline-TiO2 nanocomposite coatings on aluminum alloy 3004 (AA3004) surface has been investigated by using the galvanostatic method. The synthesized coatings were characterized by FT-IR, SEM-EDX, SEM and AFM. Optical absorption spectroscopy reveals the formation of the emeraldine oxidation state form of polyaniline-TiO2 nanocomposite. The corros...

The aniline dimer, N-(4-aminophenyl)aniline has been polymerized cleanly under mild conditions to obtain an emeraldine base form of polyaniline using [MeB(3-(Mes)Pz)3]CuCl as the catalyst and H2O2 as the oxidant, while the subsequent acidification of the emeraldine base gives the conducting emeraldine salt form of polyaniline.

A new mechanism for the formation of doped polyaniline is presented. Besides providing suitable structural and spectroscopic parameters, the new mechanism allows for the rationalization of the experimentally observed equilibrium between polaron and bipolaron defects in emeraldine salt. The magnetic behavior and the "metallic island" model for conduction in doped polyaniline are also theoretical...

Polyaniline nanocomposite using metal oxides have wide variety of applicability because its enhanced properties to that pure polyaniline. Here we employed titanium dioxide as the oxide synthesize polyaniline composite (PANi-TiO2 ) through chemical oxidative polymerization in-situ. The obtained PANi-TiO2 is tested for powder X-Ray diffractometry (XRD), & Scanning electron microscopy(SEM).

Akademisk avhandling som med tillsta nd av Kungliga Tekniska Ho gskolan i Stockholm framla gges till offentlig granskning fo r avla ggande av tekniska doktorsexamen fredagen den 10 March kl. Denna avhandling är skyddad enligt upphovsrättslagen. Alla rättigheter förbehålles. To my family God made solids, but surfaces were the work of the devil. Abstract The use of graphene and conductive polyani...

The synthesis of polyaniline- Fe2O3 nanocomposite coating on aluminum Alloy 5052 (AA5052) surface has been investigated by using the galvanostatic method. The anticorrosion performance of polyaniline-Fe2O3 coating was investigated in 3.5% NaCl solution by the open- circuit potential (OCP), Tafel polarization technique and Electrochemical Impedance Spectroscopy (EIS). The corrosion rate of polya...

background: human hair can be used as an inexpensive and accessible adsorbent to remove a variety of pollutants from air. although several studies have been done on removal of formaldehyde from wastewater by human hair, to date no study has investigated using hair to remove formaldehyde from air. therefore, the aim of this study was to remove formaldehyde from synthetic contaminated air by a re...