a new three-dimensional unit cell model has been developed for modeling three constituent phases including inclusion, interphase and matrix. the total elastic modulus of nano-composite is evaluated.  numerical results are in good agreement with the previous proposed theoretical modeling. higher matrix and inclusion elastic modulus both can dramatically influence the total elastic modulus.

Polymer nanocomposites have recently been attracting attention among researchers in electrical insulating applications from energy storage to power delivery. However, partial discharge has always been a predecessor to major faults and problems in this field. In addition, there is a lot more to explore, as neither the partial discharge characteristic in nanocomposites nor their electrical proper...

The organoclay/poly(methyl methacrylate) (PMMA) nanocomposites were prepared by in situ photopolymerization method using two solvents, ethanol and acetonitrile. The influences of organoclay loading, solvent nature and length of attached surfactant (C8 or C16) on thermal and mechanical properties were studied by thermogravimetric analysis and dynamic mechanical analysis. Alkylammonium surfactant...

This paper investigates the mechanics of hybrid shape memory polymer polystrene (PS) based nanocomposites with skeletal structures of CNFs/MWCNTs formed inside. Experimental results showed an increase of glass transition temperature (Tg) with CNF/MWCNT concentrations instead of a decrease of Tg in nanocomposites filled by spherical particles, and an increase in mechanical properties on both mac...

Polymer nanocomposites operate in applications where fluid and grease lubricants fail, and have superior tribological performance to traditional polymer composites. Nanoparticle fillers have been a part of notable reductions in the wear rate of the polymer matrix at very low loadings. Despite instances of remarkable wear reductions at unprecedented loadings (3 000 times at 0.5% loading in one c...

Title of Document: PROCESSING-STRUCTUREMICROSTRUCTUREPROPERTY RELATIONSHIPS IN POLYMER NANOCOMPOSITES Arun Kumar Kota, Doctor of Philosophy, 2007 Directed By: Professor Hugh A. Bruck, Department of Mechanical Engineering The optimal development of polymer nanocomposites using carbon nanotube (CNTs) and carbon nanofiber (CNFs) fillers requires a complete understanding of processingstructure-prop...

In this study, a hybrid Ag-ZnO nanostructured micro-filler was synthesized by the drop technique for used in plastic and medical industry. Furthermore, new antibacterial polymer nanocomposites comprising particles of Ag-ZnO up to 5 wt % and a blend of a thermoplastic polyolefin elastomer (TPO) with polypropylene were prepared using twin screw micro-compounder. The morphology and crystalline-pha...

We developed an analytical relationship between nuclear magnetic relaxation and interparticle spacings in polymer nanocomposites filled with paramagnetic-impurity-containing clay nanoparticles. Using (1)H NMR relaxometry, clay nanoparticle dispersion was quantified and agrees with interparticle spacing distributions determined from statistical analysis of TEM images. Some information on the ove...

The purpose of this study was to obtain polyamide 6 nanocomposites with national organically modified clay with three quaternary ammonium salts. The obtained results confirm the intercalation of molecules of salt in the clay layers, and a good interaction with the polymer, showing the formation of intercalated and/or partially exfoliated structures. The nanocomposites showed similar thermal sta...

This review article summarizes the preparation of polymer/carbon nanotube (CNT) nanocomposites and their applications as electrorheological (ER) fluids. These ER fluids exhibited a controllable electro-response under an applied electric field due to the presence of well-dispersed CNTs. The background, morphology, preparations, and characteristics of these materials are discussed, specifically f...