Understanding the dynamics of polymer solutions in the semidilute regime is important not only from the point of view of advancing fundamental knowledge in polymer science but also from the point of view of technological applications. The behavior of semidilute polymer solutions varies significantly with concentration and solvent quality, which are reflected in the concentration driven crossove...

We study polymer-polymer phase separation in a common good solvent by means of Monte Carlo simulations of the bond-fluctuation model. Below a critical, chain-length-dependent concentration, no phase separation occurs. For higher concentrations, the critical demixing temperature scales nonlinearly with the total monomer concentration, with a power law relatively close to a renormalization-group ...

Ž . Several polymer-coated and polymer-grafted multi-walled carbon nanotubes MWNTs were synthesized and characterized using TEM and HRTEM. The polymer-coated or polymer-grafted MWNTs formed stable solutions in DMF. Their nonlinear optical properties were investigated using 532 nm nanosecond laser pulses. These polymer–MWNT composites still possess strong nonlinear optical properties. q 2000 Els...

Macromolecular or polymeric liquids consist of polymer solutions, polymer melts, particle suspension fluids, and many biological fluids. Polymer solutions are made of polymers dissolved in solutions or solvent; polymer melts are molten polymers; particle suspension fluids consist of solid particles suspended in a matrix fluid which may be a viscous or viscoelastic fluid, blood flows consist of ...

Synthesis of densely grafted polymer brushes from good solvent polymer solutions is difficult when the surface interaction is only weakly attractive because of the strong stenc repulsion between the polymer chains To circumvent this difficulty we graft polymer layers in a poor solvent to exploit attractive polymer-polymer interactions which largely nullify the repulsive stenc interactions. This...

We map dilute or semidilute solutions of nonintersecting polymer chains onto a fluid of "soft" particles interacting via a concentration dependent effective pair potential, by inverting the pair distribution function of the centers of mass of the initial polymer chains. A similar inversion is used to derive an effective wall-polymer potential; these potentials are combined to successfully repro...

Toward a Mesoscale Model for the Dynamics of Polymer Solutions G. H. Miller1 and D. Trebotich2 ∗ 1Department of Applied Science, University of California, One Shields Avenue, Davis, CA 95616, USA and Applied Numerical Algorithms Group, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA 2Center for Applied Scientific Computing, Lawrence Livermore National Laboratory...