In this work membrane (proton exchange membrane) by using the blend polymers (polyethersulfone (PES), Expandable polystyrene (EPS), polyvenylidinefluride polymer (PVDF)) were prepared. This was modified adding organic sulfonic acid to solution precasting process, and sulfonated dipping it in diluted sulfuric (H2SO460%) post casting process. The sulfonation confirmed via FTIR spectra. characteri...