Spiro-N,N-ketal 5, consisting of a phthaloperine heterocyclic ring and a naphtha[1,8-ef][1,4]diazepine ring, was obtained along with spiro-N,N-ketal 2 via 2,2-condensation in the reaction of ninhydrin with naphthalene-1,8-diamine. Their molecular structures were elucidated by X-ray crystal structural analysis. Aside from these spiro compounds, the diazapleiadiene compound 3 formed by 1,2-conde...

Abstract Crown ethers containing an acridone or acridine unit are successfully applied opto- and electrochemical cation sensors. The heteroaromatic of these macrocycles can be in different forms during the applications, which have a strong influence on sensing behavior. Moreover, case acridono-macrocycles prototropic equilibrium takes place upon complexation, is effected by physicochemical char...

introduction: in modern societies, shift work is an essential component of daily life. since the beginning of research in shift work, researchers have been engaged in the identification of factors predicting adjustment and adaptation to shift work. the concept of adaptation and tolerance refers mainly to the biological response in terms of circadian rhythms and performance efficiency as well as...

Background & Aims: Shift work is programmed in various schedules, each has its own advantages and disadvantages. The main purposes of this study were: a) to determine common shift schedules used in petrochemical industries, b) to compare shift work health-related problems among employees working in different shift schedules and c) to recommend appropriate shift schedule. Methods: This cross...