Photoluminescent compounds showing emission color changes in response to external stimuli have received considerable attention because of their wide range of applications. Here, we report the unique photoluminescence behavior of a digold(I) coordination system with trigonal-planar Au(I) centers, [Au2(dppm)3](2+) (dppm = bis(diphenylphosphino)methane). This system shows an extremely intense phos...

Diffraction patterns were measured on a polycrystalline bcc Fe foil using a Mössbauer powder diffractometer with high sensitivity. Measurements with and without a magnetic field normal to the scattering plane showed large differences in the diffracted intensities of the different nuclear resonances. These magnetic effects on diffraction intensities were interpreted successfully with a single sc...

The stoichiometric reactions of 8-(2,6-R1-4-R2-anilide)-5,6,7-trihydroquinoline (LH) with AlR3 (R = Me or Et) afforded the aluminum complexes LAlR2 (Al1–Al5,Al1: R1 = iPr, R2 = H, R = Me; Al2: R1 = Me, R2 = H, R = Me; Al3: R1 = H, R2 = H, R = Me; Al4: R1 = Me, R2 = Me, R = Me; Al5: R1 = Me, R2 = Me, R = Et) in high yields. All aluminum complexes were characterized by NMR spectroscopy and elemen...

A novel aluminoborate (NH(4))(6)[C(5)NH(12)](6)[Al(12)B(65)O(105)(OH)(33)]·(H(2)O)(15) (QD-6), has been synthesized under mild hydrothermal conditions and characterized by IR, elemental analysis, TGA, powder and single-crystal X-ray diffractions. This compound crystallizes in the rhombohedral space group R3 (No. 148) with the lattice constants a = 23.7421(2) Å, c = 24.7699(3) Å, V = 12091.9(2) ...

Nanosized (5 to 10 nm) amorphous and crystalline nanocondensates, i.e., metallic α-phase of Zn-Cu alloy in face-centered cubic structure and (Zn,H)-codoped cuprite (Cu2O) with high-pressure-favored close-packed sublattice, were formed by pulsed laser ablation on bulk Cu65Zn35 in water and characterized by X-ray/electron diffractions and optical spectroscopy. The as-fabricated hybrid nanocondens...

Shown is that contrary to common intuition, even an arbitrarily weak attenuating mechanism is sufficient to make the background sky quite dark independently of the size of the universe and the Hubble expansion. Further shown is that such an attenuation already exists in the wave nature of light due to entrapment and diffusion from successive diffractions. This is a fundamentally new mechanism t...

Imaging diffracted waves can provide useful information about complex subsurface geology and fracture networks. Separation of diffractions from typically more intensive reflected events can be done based on specularity, which measures deviation from Snell’s law. Here, we analyze two formulations of specularity and their applicability to diffraction processing in the presence of anisotropy. We s...

The self-assembly of porous molecular nanocapsules offer unique opportunities to investigate a range interesting phenomena and applications. However, design with pre-defined properties, thorough understanding their structure-property relation is required. Here, we report the two elusive members Keplerate family, [Mo132Se60O312(H2O)72(AcO)30]42− {Mo132Se60} 1 [W72Mo60Se60O312(H2O)72(AcO)30]42− {...

Void detection is challenging due to the complexity of near-surface materials and the limited resolution of geophysical methods. Although multichannel, high-frequency, surface-wave techniques can provide reliable shear (S)-wave velocities in different geological settings, they are not suitable for detecting voids directly based on anomalies of the S-wave velocity because of limitations on the r...