The reduction using phenylsilane in a KOH-catalyzed system was applied successfully to the conversion of sulfinyl-substituted cyclopropylcarboxylates into the corresponding alcohols. The presence of sulfinyl substituents in the α-position to the carboxylate group caused a desulfinylation product formation with full regio- and stereoselectivity, instead of a carbonyl group reduction. Investigati...

A one-pot synthesis of pyrrole derivatives via reaction between activated carbonyl compounds, primary amines and 1,3-dicarbonyls under solvent-free conditions is described‎.

The effect of Maillard reaction on red blood cells (RBC) deformability was investigated. Exposure of RBC to carbonyl compounds (dl-glyceraldehyde, glyoxal, glycolaldehyde, 3-deoxyglucosone, and d-glucose) leading to Maillard reaction caused a marked decrease in RBC deformability even at 1mM level. The decrease rate depended on the kind of carbonyl compounds, in which both dl-glyceraldehyde and ...

fischer-tropsch catalysts with high activity and selectivity for olefins were produced using mordenite type sio2/al2o3= 12, 20, 28, 62 zeolite supported iron carbonyl compounds and were characterized by x-ray powder diffraction. the adsorptionof volatile fe(co)5 on the support surface was carried out under vacuum at room temperature. reduction les were monitored by vibrating sample magnetometer...