نتایج جستجو برای: rotational barrier
تعداد نتایج: 120111 فیلتر نتایج به سال:
Nowadays, nanoscale innovations in the forms of pathogen detection, active packaging, antimicrobial packaging and barrier formation are poised to elevate food packaging to new heights. Antimicrobial nanocomposite LDPE films containing ZnO nanoparticles at different concentrations (e.g. 1%, 3%, 5% and 3% nano-ZnO pulse 10% polyethylene grafted maleic anhydride (PE-g-MA), w/w pure LDPE), were p...
Background: The reactions of the whole organism that occur under the action of accelerations of rectilinear and rotational motion are factors that have a systemic effect on the cerebral blood flow. The use of hurdling performance in the structure of human physical activity can have a significant impact on the tone of the brain vessels, their elasticity and venous outflow in the development of f...
Nowadays, nanoscale innovations in the forms of pathogen detection, active packaging, antimicrobial packaging and barrier formation are poised to elevate food packaging to new heights. Antimicrobial nanocomposite LDPE films containing ZnO nanoparticles at different concentrations (e.g. 1%, 3%, 5% and 3% nano-ZnO pulse 10% polyethylene grafted maleic anhydride (PE-g-MA), w/w pure LDPE), were p...
Berthelot's equation, k,(T) = A,exp{-Dlc,T}, provides a good description of the high-pressure rate coefficient for associative reactions such as CH3 + CH3, CH3 + OH, and CH3+ H. The parameter D may be used to characterize an effective temperature-dependent barrier, AE,ff = DkiT2, which is due to the internal energy, i.e. rotational and vibrational energy, or the centrifugal barrier of the assoc...
We demonstrate the application of molecular rotational spectroscopy to measure the conformation isomerization rate of vibrationally excited pent-1-en-4-yne (pentenyne). The rotational spectra of single quantum states of pentenyne are acquired by using a combination of IR-Fourier transform microwave double-resonance spectroscopy and high-resolution, single-photon IR spectroscopy. The quantum sta...
The rotational barrier about the C S bond in fluorocarbonylsulfenyl chloride [FC(0)SC1] is investigated using the C N D O method. The results confirm the existence of planar eis and trans conformers and the higher stability of the latter, as suggested by previous vibrational results. The valence force constants in FC(0)SC1 were also calculated and the values obtained compare favourably with res...
We report inelastic neutron scattering results on hydrogen adsorbed onto samples containing single-wall carbon nanotubes. These materials have attracted considerable interest recently due to reports of high density hydrogen storage at room temperature. Inelastic neutron scattering clearly shows the ortho±para conversion of physisorbed hydrogen in a nanotube containing soot loaded with hydrogen....
The pure rotational spectrum of the ethyl radical (C2H5) has been detected for the first time with the Fourier transform millimeter-wave spectrometer. The ethyl radical is produced by discharging the C2H5I gas diluted in Ar. The 1(01)-0(00) rotational transition of the ethyl radical is observed in the frequency range from 43,680 to 43,780 MHz. The observed spectrum shows a very complicated patt...
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