Phosphosulfonic  acid  as a  multi  solid site  was  easily  prepared  from  the reaction of ammonium  dihydrogen phosphate with chlorosulfonic acid in CCl4and for improved  its  catalytic activity  was  supported  nano Silica was  extracted from  husk  rice  contains  about 95%  of  Silica the  size of  extracted nano silica was  determined  by  SEM  efficiency of  this solid acid in four comp...

cellulose sulfuric acid as a bio-polymer based solid catalyst efficiently catalyzes the selectively oxidation of sulfides to sulfoxides and thiols to disulfides using hydrogen peroxide as a green oxidant with good yields at room temperature. the developed method offers a number of advantages such as high selectivity, mild reaction conditions, simple operation, cleaner reaction profiles, low cos...

ammonium monovanadate (nh4vo3) has been devoted as an efficient, commercially available, eco-friendly and reusable catalyst for the synthesis of bis(indolyl)methanes (bims), oxindole derivatives and also michael adducts of indoles at 50 °c under solvent-free conditions. the reusability of this solid acid catalyst in addition with its selectivity has also been examined.

composite solid propellants were prepared with and without nano-alloys (ti-co, ti-ni, ti-zn), where nano-alloys used as catalyst. these nano-alloys are prepared by hydrazine reduction method. catalytic properties of these nanomaterials were measured on ammonium perchorate/hydroxyterminatedpolybutadiene propellant by thermogravimetery analysis and differential thermal analysis. both experimental...

This work and a series of successive works aim to subject various ratios of palm olein and palm stearin blends to chemical interesterification under different conditions of catalyst, temperature and time in order to obtain fat blends suitable for the production of vegetable butter (margarine) fortified with different natural vitamins and minerals and prepared by using nanotechnology. In this pa...

two simple protocols for the synthesis of tetrahydrobenzo[a]xanthenes-11-ones using nano silica phosphoric acid are reported. short reaction times, high yields, reusability of catalyst and easy workup are some advantages of these protocols.

An efficient and green protocol for the synthesis of pyrazoles derivatives by one-pot reaction of different 1,3-dicarbonyl compounds with hydrazines/hydrazides has been developed using nano-sulfated zirconia, nano-structured ZnO, nano-g-alumina and nano-ZSM-5 zeolites, as the catalyst. The optical properties of the nano-structured catalysts and organic molecules were studied. The advantages of ...

sulfonic acid functionalized sba-15 (sba-pr-so3h) as a new nanoporous acid catalyst was used in the one-pot synthesis of polyhydroquinolines derivatives via the hantzsch four component condensation reaction of aldehydes, b-ketoesters, dimedone and ammonium acetate under solvent free conditions with short reaction time in excellent yields. sba-pr-so3h was proved to be an efficient heterogeneous ...

silica-bonded n-propyldiethylenetriamine sulfamic acid (spdtsa) is employed as a recyclable heterogeneous solid acid catalyst for the synthesis of benzopyrano[2,3-d]pyrimidines  through one-pot condensation reaction of salicylaldehydes, malononitrile and secondary amines  at room temperature under solvent-free conditions. spdtsa showed much the same efficiency when used in consecutive reaction ...

An efficient and green protocol for the synthesis of pyrazoles derivatives by one-pot reaction of different 1,3-dicarbonyl compounds with hydrazines/hydrazides has been developed using nano-sulfated zirconia, nano-structured ZnO, nano-g-alumina and nano-ZSM-5 zeolites, as the catalyst. The optical properties of the nano-structured catalysts and organic molecules were studied. The advantages of ...