a chelating resin is prepared by condensation polymerization of aniline with formaldehyde andcharacterized by ft-ir, elemental analysis and studied for the preconcentration and determination of traceplatinum ion from environmental water sample using inductively coupled plasma-atomic emission spectroscopy(icp-aes). the optimum ph value for sorption of the metal ions was 5. the maximum adsorption...

A gas chromatographic technique with flame ionization detection, which is based on a solid-phase extraction (SPE) procedure using mixed-mode SPE columns, for the simultaneous quantitation of dextropropoxyphene and norpropoxyphene in urine is presented. Urine is treated with sodium hydroxide in order to rearrange, by base catalysis, norpropoxyphene to norpropoxyphene amide, which is then extract...

A simple, semi-automated, microcolumn solid-phase extraction (SPE) system is optimized for the extraction, preconcentration and HPLC analysis of seven different explosives and explosive derivatives contaminating seawater, river water and well water samples. The microcolumns were constructed from 1/16 in. O.D. PTFE tubing (1 in.=2.54 cm) packed with 0.5-1.5 mg of SPE material. LiChrolut EN or Po...

The aim of this work was to establish the best experimental conditions for the isolation of flunitrazepam and its main metabolite 7-aminoflunitrazepam from human plasma. Several mixtures of solvents (ethyl acetate, tert-butylmethyl ether, hexane, chloroform/ ethyl ether (20/80), dichloromethane / ethyl ether (20/80) and extraction cartridges (Oasis MCX , SepPak C18, Chromafix C18, Oasis HLB) we...

New materials have significant impact on development of new methods and instrumentation for chemical analysis. From the discovery of carbon nanotubes in 1991, single and multi-walled carbon nanotubes (SWCNTs and MWCNTs) -due to their high adsorption and desorption capacitieshave been employed as sorption substrates in solid-phase extraction for the preconcentration of heavy metals from diverse ...

acetonitrile used as a solvent in manufactures and affects to central nervous system from inhalation exposure. the aim of this study was to develop a micro-solid phase extraction method for  the determination of acetonitrile in the air matrix. the sampling was performed with a small diameter fused silica fiber coated with a thin film of stationary phase and was subsequently desorbed and analyze...

Many modern analytical methods deal with the trace-level determination of compounds of interest in highly complex environmental samples by means of chromatographic techniques. The introduction of a “clean” sample into an analytical instrument can make analyses easier and prolongs the equipment life. The use of solid-phase extraction (SPE) has grown and is a fertile technique of sample prepa...

Solid phase extraction (SPE) or liquid-solid extraction is poplar and growing techniques that areused to sample preparation for analysis. Metal nanoparticles have been studied for decades, and this is due to the properties that these materials do not have in bulk state. In nanoscale materials, the numbers of surface atoms is high and hence, have significant surface effects. A novel, simpl...

This chapter focuses on three widely used techniques for extraction of semivolatile organics from liquids: liquid–liquid extraction (LLE), solid-phase extraction (SPE), and solid-phase microextraction (SPME). Other techniques may be useful in selected circumstances, but these three techniques have become the extraction methods of choice for research and commercial analytical laboratories. A fou...

Abstract Sample pretreatment is one of the most crucial and error-prone steps an analytical procedure; it consents to improve selectivity sensitivity by sample clean-up pre-concentration. Nowadays, arousing interest in greener sustainable chemistry has increased development microextraction techniques as alternative preparation procedures. In this review, we aimed show two different categorizati...