UNLABELLED Laser-based diagnostics and therapeutics show promise for many neurological disorders. However, the poor transparency of cranial bone (calvaria) limits the spatial resolution and interaction depth that can be achieved, thus constraining opportunity in this regard. Herein, we report preliminary results from efforts seeking to address this limitation through use of novel transparent cr...

The electrochemical promotion of the C2H4 + O2 total oxidation reaction over a Pt catalyst, interfaced to yttrium stabilized zirconia (YSZ), has been studied at 0.25 mbar and T =...

We describe a fabrication strategy for preparing yttria-stabilized zirconia nanotube (YSZ-NT) arrays embedded in porous alumina membranes by means of template-directed atomic layer deposition (ALD) technique. The individual YSZ-NTs have a high aspect-ratio of well over 120, about ~ 110 nm in diameter, and ~ 14 µm in length. Interfacing the tube arrays with porous Pt was also introduced on the b...

In this work, thin film yttria-stabilized zirconia [YSZ] solid electrolytes were sputtered onto insulating substrates at room temperature and 600oC in order to produce different average grain sizes (~15-50 nm). For reference, polished samples of single crystal and bulk, poly-crystalline YSZ were also used. Platinum film electrodes were then sputtered on top and lithographically patterned to giv...

Anode aluminum oxide-supported thin-film fuel cells having a sub-500-nm-thick bilayered electrolyte comprising a gadolinium-doped ceria (GDC) layer and an yttria-stabilized zirconia (YSZ) layer were fabricated and electrochemically characterized in order to investigate the effect of the YSZ protective layer. The highly dense and thin YSZ layer acted as a blockage against electron and oxygen per...

The calculations performed in this study indicate that efficient deposition of tetragonal yttria-stabilized zirconia ~YSZ! by chemical vapor deposition ~CVD! is feasible using metal chloride precursors ~Zr-Y-C-O-H-Cl system!. As reported in the literature, this work demonstrates that high oxygen content is necessary to efficiently utilize metal chloride precursors for depositing tetragonal YSZ ...

In the present work, surface characterization of YSZ/Al2O3 /CeO2 plasma sprayed coatings was performed to understand characteristics. The content Yttria-stabilized zirconia (YSZ) 60 wt.% , where alumina varied from 30 38 and CeO2 2 10 wt.%, respectively. Ceramic with a different percentage variation composite materials were used increase layer strength on substrate SS-304. SEM micrographs analy...

Solid oxide fuel cell (SOFC) cathodes were prepared by infiltration of 35 wt % La0.8Sr0.2FeO3 (LSF) into porous scaffolds of three, zirconia-based electrolytes in order to determine the effect of the ionic conductivity of the electrolyte material on cathode impedances. The electrolyte scaffolds were 10 mol % Sc2O3-stabilized zirconia (ScSZ), 8 mol % Y2O3-stabilized zirconia (YSZ), and 3 mol % Y...

We use spatially resolved photoelectron spectroscopy performed in operando to identify the reaction intermediates of the hydrogen electro-oxidation reaction on yttria-stabilized zirconia (YSZ) electrolytes with Pt electrodes. We find that hydroxyl on the zirconia electrolyte is a reaction intermediate in the hydrogen oxidation reaction and that it participates in the rate-determining step. In c...