In this report, we present a simple and generic concept involving metal nanoclusters supported on metal oxide nanowires as stable and high capacity anode materials for Li-ion batteries. Specifically, SnO(2) nanowires covered with Sn nanoclusters exhibited an exceptional capacity of >800 mAhg(-1) over hundred cycles with a low capacity fading of less than 1% per cycle. Post lithiation analyses a...

We grow hydrogenated amorphous silicon-germanium alloys by the hot-wire chemical vapor deposition technique at deposition rates between 0.5 and 1.4 nanometers per second. We prepared a set of these alloys to determine the concentrations of the alloying elements as measured by various techniques. This set consists of samples throughout the range of germanium alloying from 0% (a-Si:H) to 100% (a-...

Although brasses are essentially copper and zinc alloys, they also contain other alloying elements such as lead, silicon, aluminium, iron, tin, manganese, nickel or arsenic whose presence and content are responsible for the wide variety of properties inherent to these materials. In this article, the effect of the chemical composition of brasses, considering each alloying element and the effecti...

The formation of Pd carbide (PdCx) during the synthesis of vinyl acetate (VA) was investigated over Pd/SiO2 catalysts with two different Pd particle sizes, as well as over a Pd–Au/SiO2 mixed-metal catalyst. XRD data show that PdCx was produced in the pure Pd catalysts after reaction based on the downshift of the Pd(111) and (200) XRD features. The smaller Pd particles showed greater resistance ...

Metal matrix composites are the class of composite materials finding vast applications in automotive, aircraft, defense, sports and appliance industries. A horizontal ball mill has been fabricated for milling of aluminum and SiC particles. The change in powder particle morphology during mechanical alloying of Aluminum and SiC powders using horizontal ball mill was studied. Al-SiCp composites wi...

Using scanning tunneling microscopy (STM) and first-principles local-spin-density-approximation calculations to study submonolayer films of Co (1-c)Ag (c)/Ru(0001) alloys, we have discovered a novel phase-separation mechanism. When the Ag concentration c exceeds 0.4, the surface phase separates between a dislocated, pure Ag phase and a pseudomorphically strained Co(0.6)Ag (0.4) surface alloy. W...

The different mechanisms involved in the alloying of epitaxial nanocrystals are reported in this Letter. Intermixing during growth, surface diffusion, and intraisland diffusion were investigated by varying the growth conditions and annealing environments during chemical vapor deposition. The relative importance of each mechanism was evaluated in determining a particular composition profile for ...

We prepared a new V-Rh(111) alloy with (2×2) surface geometry. The alloy system and the adsorption of CO were investigated by the photoelectron spectroscopy of the valence and core states using synchrotron radiation, and by temperature-programmed thermal desorption spectroscopy (TPD). The obtained results indicate that the vanadium atoms in the prepared alloy were situated mainly in the subsurf...

Alloying addition, as a means of improving mechanical properties and saving on costs of materials, has been applied to a broad range of uses and products in the metallurgical fields. In the field of bulk metallic glasses (BMGs), alloying additions have also proven to play effective and important roles in promoting glass formation, enhancing thermal stability and improving plasticity of the mate...

Steel production involves three basic steps. At first, the heat source is to be produced to melt the iron ore. Next in a furnace iron is melted. Lastly, to produce steel the molten iron is processed. The advantage of steel over iron is greatly enhanced strength. The properties of steel are highly reliant on the amount of alloying elements, so that their levels are carefully controlled during it...