N-Acetylation of (2,3,4,6-tetra-O-acetyl-a-D-glucopyranosyl) (2,3,4,6-tetra-0-acetyl-/?-D-glucopyranosyl)amine or bis(2,3,4,6-tetra-0-acetyl-/3-D-glucopyranosyl)amine afforded N-acetyl-bis(2,3, 4,6-tetra-0-acetyl-/3-D-glucopyranosyl)amine; deacetylation of the latter gave Af-acetyl-di-/3-Dglucopyranosylamine. Similarly, TV-acetylation of bis(2,3,4-tri-0-acetyl-/3-L-rhamnopyranosyl)amine led to ...

The asymmetric unit of the title compound, 2C15H16N6O3·C3H7NO·H2O, contains two independent ethyl 6-methyl-2-oxo-4-[4-(1H-tetra-zol-5-yl)phen-yl]-1,2,3,4-tetra-hydro-pyrim-id-ine-5-carboxyl-ate mol-ecules, in which the dihedral angles between the tetra-zole and benzene rings are 20.54 (12) and 12.13 (12)°. An intra-molecular C-H⋯O hydrogen bond occurs in each mol-ecule. In the crystal, N-H⋯O, N...

In the title compound, [Ni(C(8)H(4)O(4))(C(36)H(44)N(4)O(4))](n), the Ni(II) atom is coordinated in a distorted octa-hedral geometry by the four N atoms of the 1,12,15,26-tetra-aza-5,8,19,22-tetra-oxa-3,4:9,10:17,18:23,24-tetra-benzocyclo-octa-cosane ligand and two O atoms from the terephthalate dianions. The Ni(II) atoms, which lie on inversion centres, are linked via terephthalate ligands to ...

In the title complex, [Ag(C(3)H(3)N(4)O(2))](n), the Ag(I) atom is four-coordinated in a slightly distorted tetra-hedral coordination geometry by two N atoms from two tetra-zole-1-acetate (tza) ligands and two O atoms from the other two tza ligands. The tza ligand bridges two Ag atoms through the carboxyl-ate O atoms and simultaneously binds to the other two Ag atoms through the tetra-zole N at...

The title compound, C(4)H(12)N(+)·C(8)H(11)NO(5)PS(-), was obtained from tetra-methyl-ammonium hydroxide and dimeth-yl(phenyl-sulfon-yl)amido-phosphate. The tetra-methyl-ammonium cation has a slightly distorted tetra-hedral configuration and the N-C bond lengths lie in the range 1.457 (3)-1.492 (3) Å. In the crystal, no classical hydrogen bonds are observed between the cation and the anion.

The crystal structure of the title compound, C(15)H(11)FN(6)S, forms a three-dimensional network stabilized by π-π inter-actions between the imidazole core and the tetra-zole ring of the tetra-zolopyridine-unit; the centroid-centroid distance is 3.627 (1) Å. The crystal structure also displays bifurcated N-H⋯(N,N) hydrogen bonding and C-H⋯F inter-actions. The former involve the NH H atom of the...

The title compound, [Zn(C(6)H(4)N(5))(2)(H(2)O)(4)]·4H(2)O, was synthesized by the hydro-thermal reaction of Zn(CH(3)COO)(2)·2H(2)O with 3-(2H-tetra-zol-5-yl)pyridine. The Zn(II) ion is located on an inversion center and is coordinated by two pyridine N atoms from two 5-(3-pyrid-yl)tetra-zolide ligands and four coordinated water mol-ecules in a slightly distorted octa-hedral geometry. The dihed...