Na promoted Pt/TiO2 catalysts have been studied under high severity, near equilibrium, conditions for use as a single stage WGS catalyst. Addition of 3 wt% Na to a 1 wt% Pt/TiO2 catalyst has been found to improve water gas shift activity significantly compared to Pt/TiO2, Pt/CeO2, and Pt–Re/TiO2 catalysts. This catalyst is stable when the reaction temperature is higher than 250 C. Deactivation ...

The aim of this study was to use a life-cycle perspective to model the quantities of engineered nanoparticles released into the environment. Three types of nanoparticles were studied: nano silver (nano-Ag), nano TiO2 (nano-TiO2), and carbon nanotubes (CNT). The quantification was based on a substance flow analysis from products to air, soil, and water in Switzerland. The following parameters we...

Raman spectroscopy is known as a powerful technique for solid catalyst characterization as it provides vibrational fingerprints of (metal) oxides, reactants, and products. It can even become a strong surface-sensitive technique by implementing shell-isolated surface-enhanced Raman spectroscopy (SHINERS). Au@TiO2 and Au@SiO2 shell-isolated nanoparticles (SHINs) of various sizes were therefore pr...

The pulmonary damage induced by nanosized titanium dioxide (nano-TiO2) is of great concern, but the mechanism of how this damage may be incurred has yet to be elucidated. Here, we examined how multiple genes may be affected by nano-TiO2 exposure to contribute to the observed damage. The results suggest that long-term exposure to nano-TiO2 led to significant increases in inflammatory cells, and ...

When Au is subdivided to the nanoscale its reactivity changes from an inert nature to one of incredible reactivity which is not replicated by other catalysts. When dispersed onto metal oxides such as TiO2, nano-Au has shown high reactivities for a multitude of reduction and oxidation reactions of industrial importance with potential and current uses such as, CO oxidation, NO x reduction, purifi...

Titanium dioxide nanoparticles are photoactive and produce reactive oxygen species under natural sunlight. Reactive oxygen species can be detrimental to many organisms, causing oxidative damage, cell injury, and death. Most studies investigating TiO2 nanoparticle toxicity did not consider photoactivation and performed tests either in dark conditions or under artificial lighting that did not sim...

The release of nanomaterials from products and applications that are used by industry and consumers has only been studied to a very limited extent. The amount and the characteristics of the released particles determine the potential environmental exposure. In this work we investigated the release of Ti from paints containing pigment-TiO2 and nano-TiO2. Panels covered with paint with and without...

The photodegradation of Direct Blue 258, a member of the group of azo dyes which are commonly used in the various branches of the industry, was studied. The photostability of this dye was not previously surveyed. Photocatalytic degradation method was evaluated. The both light source include solar simulated (UV 400 W lamp) and sun light (E= 400 W/m2) and titanium dioxide nanoparticles were used ...

The photodegradation of Direct Blue 258, a member of the group of azo dyes which are commonly used in the various branches of the industry, was studied. The photostability of this dye was not previously surveyed. Photocatalytic degradation method was evaluated. The both light source include solar simulated (UV 400 W lamp) and sun light (E= 400 W/m2) and titanium dioxide nanoparticles were used ...

–In this study cotton fabric was pretreated with nano TiO2 (<100nm) particles by Pad-Dry-Cure technique. The deposition of nano particles on the fabric was observed by SEM and elementally analyzed by oxford –Inca software using SEM. The treated fabric was analyzed for the change in their physical, biological and functional properties compared to the untreated cotton fabric. Very encouraging res...