K. A. Juggernauth , K. Sun , A. J. Hart , and S. Daly c a Macromolecular Science and Research Center, University of Michigan, 2455 Hayward St, Ann Arbor, MI 48105 b Electron Microbeam Analysis Laboratory, Department of Materials Science and Engineering, University of Michigan, 2455 Hayward St, Ann Arbor, MI 48105 c Department of Mechanical Engineering, University of Michigan, 2350 Hayward St, A...

The effect of the neutral surfactant dodecylamine and octadecylamine on the synthesis of TiO2-based nanostructures by the treatment of anatase with NaOH under hydrothermal conditions in the temperature range 120-150 degrees C and different reaction times was investigated. The products analyzed by electron microscopy, X-ray diffraction, FT-IR and elemental analysis contains--depending of the ami...

A quick and dependable technique has been developed that allows us to selectively produce anodized TiO2 in the form of nanotubes. The process employs mild chemical conditions and ambient temperature. The method can consistently produce nearly 100% surface coverage of nanotubes within 10 min of anodizing. Anodizing in relatively high pH electrolytes for 1 hour permitted us to produce nanotubes o...

The photocatalytic antibacterial properties of anodic titanium oxide (ATO) nanotubes in the anatase structure derived from annealing at 450°C or 550°C N-doping treatment were tested on Escherichia coli under UV-A, visible light illumi-nation, and dark conditions. Under UV-A illumination conditions, most cases, E. cultures containing ATO different treatments showed either no slight differences t...

A facile method to produce conformal coated reduced graphene oxide (rGO) on vertically aligned titanium oxide (TiO2) nanotubes three dimensional (3D) arrays (NTAs) is demonstrated for enhanced field emission display applications. These engineered nano arrays exhibit efficient electron field emission properties such as high field emission current density (80 mA/cm(2)), low turn-on field (1.0 V/μ...

The mechanism of the one-order-of-magnitude increase in the density of vertically aligned carbon nanotubes (CNTs) achieved by a recently developed thermal chemical vapor deposition process was studied using synchrotron radiation spectroscopic techniques. In the developed process, a Ti film is used as the underlayer for an Fe catalyst film. A characteristic point of this process is that C2H2 fee...

The objective of this study is to investigate the effect of cyclic precalcification treatment to impart bioactive properties for titanium implants. Before precalcification, the titanium implants were subjected to blasting using hydroxyapatite (HAp), a resorbable blasting medium (RBM treated), and anodized using an electrolyte containing glycerol, H2O, and NH4F. Precalcification treatment was pe...

Large-sized titanium dioxide (TiO2) nanotube arrays with an outer diameter of approximately 500 nm have been successfully synthesized by potentiostatic anodization at 180 V in a used electrolyte with the addition of 1.5 M lactic acid. It is found that the synthesized large-diameter TiO2 nanotube array shows a superior light scattering ability, which can be used as a light scattering layer to si...

Degradation of Acid Red 4 (AR4) by photocatalytic processes with TiO2 nanotube arrays (TNTs) of various dimensions was carried out in this study. TNTs was fabricated by the anodization of titanium foil in electrolyte containing fluoride. The dimension and the induced photocurrent of TNTs were determined by a field-emission scanning electron microscopy and a potentialstat/galvanostat, respective...

To understand the effect of substrate microstructure on the formation of TiO2 nanotubes, anodic oxidizations of commercially pure titanium subjected to surface mechanical attrition treatment (SMATed-Ti) and unSMATed-Ti in a glycol solution containing NH4F and small amounts of water were investigated. The SMATed-Ti exhibit a nanocrystallized surface layer containing a high density of grain bound...