-The conditions under which an exchanger phase will behave as an ideal mixture are established from thermodynamic principles. It is shown that, if a stoichiometric cation-exchange reaction is reversible, the exchanger phase will exhibit ideal behavior if the Vanselow selectivity coefficient is independent of the exchanger composition. This criterion is applied to some recently published data fo...

The effects of trace metal contaminants (lead, cadmium, and mercury) on the immunologic responses of rats infected with Trypanosoma lewisi were investigated to determine whether chronic exposures to subclinical levels of these metals have adverse effects on the host's ability to respond to an infective agent.Earlier and higher levels of parasitemia were detected in animals exposed to cadmium, l...

The capability of high-speed countercurrent chromatography (HSCCC) has been investigated for enrichment and determination of metal ions at trace levels. Separation of selected divalent metal ions was performed using a small coiled column. A hexane solution of 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (EHPA) was employed as the stationary phase. Loaded divalent metal ions such as Ni, C...

Earth’s core may contain C, and it has been suggested that C in the core could stabilize the formation of a solid inner core composed of Fe3C. We experimentally examined the Fe–C system at a pressure of 5 GPa and determined the Fe–C phase diagram at this pressure. In addition, we measured solid metal/liquid metal partition coefficients for 17 trace elements and examined the partitioning behavio...

background: this cross sectional study was carried out to determine the relationship between metal dust exposure and respiratory health in male steel workers in terengganu, malaysia. methods: subjects were interviewed using a structured questionnaire from british medical research council (bmrc) questionnaire regarding respiratory symptoms and were examined their lung function using spirometer. ...

A one-step preconcentration method using two columns in series was used to partition trace metals in natural waters into several operationally defined fractions. The water passed through a Chelex-100 cation exchange column to collect dissolved labile trace metals and then through an AG MP-1 macroporous resin column to collect trace metals complexed with natural organic matter. A third fraction ...

Ion-exchange membranes were used in conjunction with neutron-activation analysis and anodic stripping voltammetry for the determination of certain trace metal ions. The various parameters which govern the applicability, limitations and sensitivity of the methods were investigated. A new membrane "barrier" electrode assembly was introduced and found to be useful for the anodic stripping determin...

For more than 100 years, the wetland sediments at the Indiana Dunes National Lakeshore (IDNL) and adjacent Indiana Dunes State Park have received atmospheric input of trace metals from industrial sources located upwind and to the west. The objective of this study was to document the extent and magnitude of this trace metal pollution both aerially and with depth within the IDNL, and to identify ...

Earth's core may contain C, and it has been suggested that C in the core could stabilize the formation of a solid inner core composed of Fe 3 C. We experimentally examined the Fe-C system at a pressure of 5 GPa and determined the Fe-C phase diagram at this pressure. In addition, we measured solid metal/liquid metal partition coefficients for 17 trace elements and examined the partitioning behav...