Computations at the CASPT2, CBS-QB3, and B3LYP levels of theory demonstrate that -substitution of vinyl cations with π-donors switches the ground state of these ions from the familiar closedshell singlet state to a carbene-like triplet state similar to the electronic state of triplet phenyl cations. Although the parent vinyl cation is a ground-state singlet species with a very large energy gap ...

Computations at the CASPT2, CBS-QB3, and B3LYP levels of theory demonstrate that beta-substitution of vinyl cations with pi-donors switches the ground state of these ions from the familiar closed-shell singlet state to a carbene-like triplet state similar to the electronic state of triplet phenyl cations. Although the parent vinyl cation is a ground-state singlet species with a very large energ...

Spin-lattice relaxation times T1 of photoexcited triplets (3)C70 in glassy decalin were obtained from electron spin echo inversion recovery dependences. In the range 30-100 K, the temperature dependence of T1 was fitted by the Arrhenius law with an activation energy of 172 cm(-1). This indicates that the dominant relaxation process of (3)C70 is described by an Orbach-Aminov mechanism involving ...

Triplet emitter materials present attractive possibilities for optimizations of organic/organometallic light emitting diodes (OLEDs). This is due to the significantly higher efficiencies obtainable with these compounds as compared to organic emitters. In this contribution, first a schematic introduction is given, how an OLED device is built-up and why multi-layer structures are preferred. Then ...

Neutrino oscillation experiments reveal that neutrinos have very small but finite masses. Since neutrinos have no masses in the standard model, we need to extend the standard model to induce the neutrino masses which coincide with the results of the neutrino oscillation experiments. It is possible that neutrino can have both of Dirac mass and Majorana mass. Majorana mass has the feature that it...

Conformal field theories with ŝl(2)−1/2 symmetry are studied with a view to investigating logarithmic structures. Applying the parafermionic coset construction to the non-logarithmic theory, a part of the structure of the triplet model is uncovered. In particular, the coset theory is shown to admit the triplet W -algebra as a chiral algebra. This motivates the introduction of an augmented ŝl(2)...

We review some recent extensions of the Ginzburg-Landau model able to describe several properties of non-conventional superconductors. In the first extension, s-wave superconductors endowed with two different critical temperatures are considered, their main thermodynamical and magnetic properties being calculated and discussed. Instead in the second extension we describe spin-triplet supercondu...

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