SINCE Soret [1883] described an ultraviolet absorption band in three of the haemoglobin series, numerous investigations have been carried out on the ultraviolet absorption spectrum of the blood pigment and its immediate derivatives. The haemoglobin compounds were investigated by Gamgee [1895] who pointed out that there was a specific ultraviolet band common to oxyhaemoglobin, reduced haemoglobi...

Novel pyrazole derivatives 2-7 are synthesized by the reaction of 2-substituted 1,3-bis(dimethylamino)-trimethinium salts with phenyl hydrazine in acetonitrile as the solvent. This method has some advantages of high yields (78-85%), simplicity of the process and easy of control. The ultraviolet spectral behavior of the synthesized compounds is examined in CDCl3 and their structures were charact...

The complex formation between Cu (I) Cl and Cl was investigated in a 1 M HC104 ionic medium at 22 °C. In saturated CuCl(s) — Cl'-solutions over the concentration range 0 — 0.25 M Cl" the only complexes observed are CuCl2" and CuCl32-. The complex constants for the formation of these complexes are l o g ß n = —1.31 and log / ? 1 2 = —1.6 respectively. The UV-absorption spectra of CuCl2~ and CuCl...

The absorption spectra of proteins have been made the subject of considerable study. For the greatest number of proteins there has been demonstrated a broad band with a peak at about 280 rnp and a minimum, on the short wave-length side, at about 250 m,u (1). From quantitative studies of simple proteins, this band could be correlated with the presence of tyrosine, tryptophan, and phenylalanine (...

We examined the 229 nm deep-ultraviolet resonance Raman (DUVRR) spectra of solution and solid-state trinitrotoluene (TNT) and its solution and solid-state photochemistry. Although TNT photodegrades with a solution quantum yield of ϕ ∼ 0.015, the initial photoproducts show DUVRR spectra extraordinarily similar to pure TNT, due to the similar photoproduct enhancement of the -NO2 stretching vibrat...

The nonoxidizing catalytic noble metal rhodium is introduced for ultraviolet plasmonics. Planar tripods of 8 nm Rh nanoparticles, synthesized by a modified polyol reduction method, have a calculated local surface plasmon resonance near 330 nm. By attaching p-aminothiophenol, local field-enhanced Raman spectra and accelerated photodamage were observed under near-resonant ultraviolet illumination...

Ultraviolet spectra of seven comets taken with the same instrument are presented. Comets P/Encke (1980), P/Tuttle (1980 h), P/Stephan-Oterma (1980 g), and Meier (1980 q) were observed during November-December 1980 with the International Ultraviolet Explorer (IUE) satellite observatory, while comets P/Borrelly (1980 i) and Panther (1980 u) were observed with IUE on 6 March 1981. The spectra of t...

Sr5Nb4O15 – Nb2O5 nanocomposites were synthesized in 2 and 4 M KOH aqueous solutions, via a non-stoichiometric 1:2 Sr:Nb molar ratio hydrothermal method at 160°C for 48 h (S1 and S2, respectively). Sr(NO3)2 and Nb2O5 were used as raw materials. The synthesized nanomaterials were characterized by powder X-Ray diffraction (PXRD) technique. It was found that Sr5Nb4O15 has been crystallized in hexa...

Nickel oxide (NiO) nano-size powder is synthesized using nickel (II) acetate tetrahydrate, sodium lauryl sulfate (SLS) and ammonia as precursors. Applied surfactant is anionic surfactant. The sample was characterized by FT-IR, X-ray diffraction (XRD), scanning electron microscopy (SEM). The results obtained confirm the presence of nickel oxide nano-powders produced during chemical precipitation...