Soils in Technical Area 16 at Los Alamos National Laboratory (LANL) are severely contaminated from past explosives testing and research. Our objective was to conduct laboratory and pilot-scale experiments to determine if zerovalent iron (Fe(0)) could effectively transform RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine) in two LANL soils that differed in physicochemical properties (Soils A and B)....

Electron transfer from zerovalent iron (Fe0) to targeted contaminants is affected by initial Fe0 composition, the oxides formed during corrosion, and surrounding electrolytes. We previously observed enhanced metolachlor destruction by Fe0 when iron or aluminum salts were present in the aqueous matrix and Eh/pH conditions favored formation of green rusts. To understand these enhanced destruction...

The transport of microscale carbonyl iron powder suspensions modified with anionic homopolymers was studied in water-saturated sand columns containing well-dispersed hydrophobic sand grains. Sand grains functionalized with hexadecyltrimethoxysilane were coated with a eutectic mixture of dichlorobenzenes that was solid at -10 °C and was mixed by grinding with unmodified sand grains. The dichloro...

A feasibility study was conducted using slags from six grey-iron foundries to evaluate their potential as reactive media for permeable reactive barriers (PRBs) to remove aqueous trichloroethylene (TCE) from groundwater. Batch tests indicated that the slags exhibit varying degrees of reactivity ranging from nonreactive to reactivity comparable to that obtained with commercially available granula...

Six soil amendments including municipal solid waste compost (MSWC), coal fly ash (CFA), rice husk biochar prepared at 300°C (B300) and 600°C (B600), zerovalent iron (Fe0), and zerovalent manganese (Mn0) were evaluated to determine their ability to reduce mobility of chromium (Cr) in a Cr-spiked soil. The Cr-spiked soil samples were separately incubated with selected amendments at 2 and 5% [weig...

A novel zerovalent ruthenium complex with a π-acidic ligand, Ru(η (6)-cyclooctatriene)(η (2)-dimethyl fumarate)2 (1), was prepared from Ru(η (4)-cyclooctadiene)(η (6)-cyclooctatriene) [Ru(cod)(cot)]. Complex 1 or Ru(cod)(cot) catalyzes various new carbon-carbon bond-forming reactions that include the [2 + 2] cycloaddition of alkenes and alkynes via ruthenacycles, the creation of a new hydrocarb...