Piezoelectric Nanogenerators (PENGs), which can convert ambient mechanical stimuli into electrical energy, are held in high regard due to their cost-effectiveness, energy harvesting applications, and potential as self-powered sensors. We report an aluminum-doped zinc stannate (ZnSnO 3 ) PENG that achieve outputs with respect the external force. In order enrich piezoelectric mechanics, a low-tem...

The title salt, [(CH(3))(2)NH(2)][Sn(C(6)H(5))(3)Cl(2)], was obtained as a by-product of the reaction between bis-(dimethyl-ammonium) oxalate and triphenyl-tin chloride. In the stannate anion, the trigonal-bipyramidal coordination environment of the Sn(IV) atom is defined by the phenyl groups in equatorial and the Cl atoms in axial positions. The cations are connected to adjacent anions through...

The crystal structure of the title compound, (C6H14N)3[Sn(C2O4)2Cl2]Cl·H2O, contains three cyclo-hexyl-ammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water mol-ecule. The cyclo-hexyl-ammonium cations adopt chair conformations. In the complex anion, two bidentate oxalate ligands and two chloride anions in cis positions coordinate octa-hedrally to the cent...

The title compound, (C6H14N)2[Sn(C6H5)2Cl4], contains cyclo-hexyl-ammonium cations in general positions and a stannate(IV) anion that is located on a twofold rotation axis. The Sn(IV) atom in the complex anion is surrounded by four Cl(-) ligands and two trans-phenyl groups in a distorted octa-hedral configuration. The anions are connected with the cations through N-H⋯Cl hydrogen bonds. Every ca...

The Sn atom in the title substituted pyridinium stannate bromo-3,4-dichloro-benzene solvate, (C(7)H(11)N(2))(2)[SnBr(4)(C(6)H(3)Cl(2))(2)]·C(6)H(3)BrCl(2), lies on a twofold axis within an octa-hedral C(2)Br(4) donor set. Each cation forms an N-H⋯Br hydrogen bond to one of the Br atoms of the anion. The solvent mol-ecule is disordered about the twofold rotation axis with equal occupancy. The cr...

Bis[triamminesilver(I)] bis-[diamminesilver(I)] hexa-fluorido-stannate(IV) difluoride, [Ag(NH3)3]2[Ag(NH3)2]2[SnF6]F2, was obtained in the form of colourless crystals from the reaction of CsAgSnF7 in anhydrous ammonia. Two different ammine complexes of silver(I) are present in the structure, i.e. a linear diammine and a T-shaped triammine complex. The ammine silver(I) complexes show Ag⋯Ag dista...

The reaction of the lithium tris(2-pyridyl)stannate [LiSn(2-py)3] (py6OtBu = C5H3N-6-OtBu), 1, with the element(II) amides E{N(SiMe3)2}2 (E = Sn, Pb) afforded complexes [LiE{Sn(2-py)3}3] for E = Sn (2) and E = Pb (3), which reveal three Sn–E bonds each. Compounds 2 and 3 have been characterized by solution NMR spectroscopy and X-ray crystallographic studies. Large 1J(119Sn–119/117Sn) as well as...

In the title compound, (C(12)H(24)N)[Sn(CH(3))(3)(C(6)H(6)O(3)P)(2)], the SnMe(3) residues are axially coordinated by two monodentate [PhPO(3)H](-) anions, leading to a trigonal-bipyramidal geometry for the Sn(IV) atom. The two [SnMe(3)(PhPO(3)H)(2)](-) anions in the unit cell are associated into infinite chains along the a axis by O-H⋯O hydrogen bonds involving the hy-droxy group of the hydrog...