نتایج جستجو برای: کاتالیست zsm 5
تعداد نتایج: 1217864 فیلتر نتایج به سال:
LaTonia Belcher and Sarah Teren under the supervision of: John Regalbuto and Marc Schreier Department of Chemical Engineering University of Illinois at Chicago ______________________________________________________________________ ABSTRACT: Currently the procedure on how to make over exchanged Cu-ZSM-5 is well known and can be made at many different exchange rates [1]. However, no one understan...
فرایند دو مرحله ای ارتقای باقیمانده برج خلاء در این تحقیق مورد مطالعه و بررسی قرار گرفته است. اولین مرحله شامل یک ارتقا از نوع شکست حرارتی بر روی خوراک خام می باشد. محصول شکسته شده در مرحله اول، وارد مرحله دوم شده و شکست کاتالیستی در فاز مایع بر روی آن انجام می گیرد. عملکرد کاتالیستی چهار کاتالیست نانو حفره مورد ارزیابی قرار گرفته است. همچنین بررسی اثر دمای واکنش و نسبت کاتالیست به خوراک بر روی...
As stock of crude oil is limited, new resources for fuel and petrochemicals are required to be developed. Natural gas or biogas can be easily converted into methanol which can be converted into gasoline and olefins. This study uses zeolite catalyst (ZSM-5) and its modification by Ni to convert methanol to hydrocarbons (MTH). Catalysts are studied at different temperatures and at different loadi...
A continuous microwave equipment (CME) has been successfully developed in order to achieve an extremely rapid and mass production for ZSM-5 and NaY zeolite. A precursor mixture for synthesis of ZSM-5 was prepared by mixing aluminosilicate gel with a nanoseed solution obtained under microwave irradiation, and pumped continuously into the CME. Duration time in the CME was 5 min to accomplish the ...
The absorption of carbon monoxide with H-ZSM-5 and metal-substituted Li-ZSM-5 zeolites has been investigated by Ž . using both cluster and embedded cluster approaches at the HFr6–31G d,p level of theory. For the H-ZSM-5 zeolite, the binding energy of CO on a 3T quantum cluster is predicted to be 2.25 kcalrmol for the C-bound complex. The O-bound complex was found to be less stable by about 0.84...
گاز سنتز مخلوطی از هیدروژن و مونوکسید کربن که بی بو، بی رنگ و سمی است. رفرمینگ کاتالیستی متان، دو گاز گلخانه ایی مشکل ساز کربن دی اکسید و متان را به گاز سنتز تبدیل می کند. هدف اصلی ازکارحاضر بررسی عملکرد کاتالیست lanio3 بر روی پایه های زئولیتی (zsm-5 ، h-mor-40، h-mfi-90) در واکنش رفرمینگ خشک متان می باشد. هدف دیگر از این کار، بررسی تاثیر شستشوی h-mfi-90 با محلول naoh در واکنش رفرمینگ خشک متان ...
Adsorption of carbonmonoxide on the silver ion-exchanged Ag-ZSM-5 zeolite has been studied using both quantum cluster and embedded cluster at the models B3LYP/6-31G(d,p) level of theory. The Ag...Oz distance in Ag-ZSM-5 complexes is predicted to be 2.26 Å for the quantum cluster and 2.32 Å for the embedded cluster, the latter is in agreement with the experimental value of 2.30 + 0.03 Å. The opt...
Hierarchical ZSM-5 zeolite is hydrothermally synthesized in a single step with cetyltrimethylammonium (CTA) hydroxide acting as mesoporogen and structure-directing agent. Essential to this synthesis is the replacement of NaOH with KOH. An in-depth solid-state NMR study reveals that, after early electrostatic interaction between condensed silica and the head group of CTA, ZSM-5 crystallizes arou...
Formic acid oxidation reaction (FAOR) was studied using different platinum-zeolites hybrid catalysts. The catalysts were prepared by addition of two forms the ZSM-5 zeolite (ZSM-5-H+ and ZSM-5-NH4+) to an ink containing Vulcan carbon support Pt nanoparticles (NPs). TEM images demonstrate a proper mixture components in good dispersion NPs mainly over carbon. Both zeolites (ZSM-5-NH4+ ZSM-5-H+) a...
Mesoporous ZSM-5 prepared by alkaline treatment was demonstrated as an efficient catalyst for the cellulose hydrolysis in ionic liquid (IL), affording a high yield of reducing sugar. It was demonstrated that mesoporous ZSM-5 (SiO₂/Al₂O₃ = 38) had 76.2% cellulose conversion and 49.6% yield of total reducing sugar (TRS). In comparison, the conventional ZSM-5 had a mere 41.3% cellulose conversion ...
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