The hydrothermal synthesis of two new inorganic-organic hybrid materials in which PDA (PDA = 1,10-phenanthroline-2,9-dicarboxylate) is connected to a well-defined Keggin-type polyoxometalate anion (POM) and a Ln(III) cation (POM = [SiW12O40]4−; Ln = Eu3+ (1), Er3+ (2)), are reported. These hybrids are characterized by elemental analyses, IR spectra and single-crystal X-ray diffraction. Single-c...

The title compound, octaaqua-(hydrogenfluorido)dicopper(II) hexa-fluoridoferrate(III) dihydrate, was synthesized under hydro-thermal conditions. The Cu atom is coordinated by one F and five O atoms within a highly distorted octa-hedron, forming dimeric [Cu(2)(H(2)O)(8)HF(2)](3+) units by edge sharing. These units are hydrogen bonded to [FeF(6)](3-) anions and to an inter-stitial water mol-ecule...

An innovative full-scale implementation of a permeable reactive barrier, consisting of a double-row of cylinders filled with zerovalent iron shavings, for chromate remediation was monitored over four years. Solid samples were analyzed to elucidate (i) the relevant corrosion mechanisms and products, (ii) the pathways of chromate reduction and immobilization, and (iii) the long-term performance o...

Chromium (VI), also known as hexavalent chromium, is the second most stable oxidation state of chromium. Rarely occurring naturally, most chromium (VI) compounds are manufactured (products or by-products). Chromium (VI) can be reduced to the more stable chromium (III) in the presence of reducing agents (e.g. iron) or oxidizable organic matter (OSHA, 2006). Selected chemical and physical propert...