The formation of 8-SH-cGMP from the reaction between hydrogen sulfide and 8-nitro-guanosine-3',5'-cyclic monophosphate in the presence of thiols does not take place by nucleophilic attack of the hydrosulfide anion, as previously proposed, but first involves the formation of reactive species containing sulfane sulfur, like persulfides.

Micro-patterned Ni thin films with well-defined 2D-structures are useful to examine electrochemical reaction kinetics of SOFC anodes. In this work, an electrode preparation method is developed yielding stable Ni pattern electrodes on YSZ, which facilitate long term measurements. Moreover, these stable electrodes allowed investigating the effect of the YSZ substrate orientation on the polarizati...

Oral malodor is an unpleasant condition experienced by most individuals around the world. Volatile sulfur compounds (VSCs) may be the main source of oral malodor both in humans and dogs. The purpose of this study was to examine the suitability for measurement of oral malodor levels in dogs using OralChromaTM, a portable gas chromatograph developed for human use. Oral malodor and periodontal dis...

Hydrogen sulfide (H2S) is an important biological signaling agent that exerts action on numerous (patho)physiological processes. Once generated, H2S can be oxidized to generate reductant-labile sulfane sulfur pools, which include hydrodisulfides/persulfides. Despite the importance of hydrodisulfides in H2S storage and signaling, little is known about the physical properties or chemical reactivi...

Technetium-99m sulfur colloid ( mTc-SC) has been useful in reticuloendothelial imaging, and in particular in liver/spleen and more recently bone marrow scintigraphy. Technetium99m SC can also be employed to localize acute gastrointestinal bleeding and has been used in lung ventilation studies. The standard radiolabeling method requires a heating period in a boiling water bath. A comparison of a...

UNLABELLED We report the synthesis and preliminary biologic testing of a synthetic macromolecule, (99m)Tc-diethylenetriaminepentaacetic acid (DTPA)--mannosyl-dextran, for sentinel node detection. METHODS Synthesis started with a 2-step process that attaches a high density of amino-terminated leashes to a dextran backbone. Allyl-bromide was reacted with pharmaceutical-grade dextran to yield al...

Several bioreactor systems are used for biological treatment of hydrogen sulfide. Among these, airlift bioreactors are promising for the bioconversion of hydrogen sulfide into elemental sulfur. The performance of airlift bioreactors is not adequately understood, particularly when directly fed with hydrogen sulfide gas. The objective of this paper is to investigate the performance of an airlift ...

which oxidizes H 2 S to persulfide. SQRs were initially identified in invertebrates, and their mammalian counterpart SQRs were later discovered (Theissen et al., 2003; Theissen and Martin, 2008). In the presence of O 2 and water, sulfur dioxygenase oxidizes persulfide to sulfite, which is combined with another persulfide molecule by sulfur transferase rhodanese in order to producing thiosulfate...

Palladium-catalyzed carbothiolation of terminal alkynes with azolyl sulfides affords various 2-(azolyl)alkenyl sulfides with perfect regio- and stereoselectivities. The present addition reaction proceeded through a direct cleavage of carbon-sulfur bonds in azolyl sulfides. The resulting adducts that are useful intermediates in organic synthesis are further transformed to multisubstituted olefin...

Halitosis and olfactory dysfunction may disrupt an individual's quality of life remarkably. One may ask whether halitosis has effects on olfactory functions or not? Thus, the aim of this study was to evaluate the olfactory abilities of subjects with chronic halitosis evaluated using the measurements of volatile sulfur compounds. This study was carried out in 77 subjects, with a mean age of 40.1...