نتایج جستجو برای: activation entropy
تعداد نتایج: 491900 فیلتر نتایج به سال:
We analyze the dynamics of model supercooled liquids in a temperature regime where predictions of mode coupling theory (MCT) are known to be valid qualitatively. In this regime, the Adam-Gibbs (AG) relation, based on an activation picture of dynamics, also describes the dynamics satisfactorily, and we explore the mutual consistency and interrelation of these descriptions. Although entropy and d...
Computerized fractal analysis was used in the present work for objective characterization of the entropy of the platelet contour in in vitro stimulated platelets by low level thrombin (0.02 U/ml), collected from healthy individuals and observed by means of transmission electron microscopy. Platelet boundaries were extracted by means of automatically image analysis. Information dimension of the ...
Time and temperature dependence of the binding of 3H-dihydroalprenolol (3H-DHA) to beta-adrenergic receptors in rat cerebral cortex is described. The kinetic data obtained suggest that 3H-DHA binding proceeds through a two-step reaction scheme consisting of a bimolecular association step followed by an unimolecular internal conversion of the radioligand receptor complex (isomerisation). Equilib...
The Rényi entropy is a generalization of Shannon entropy to a one-parameter family of entropies. Tsallis entropy too is a generalization of Shannon entropy. The measure for Tsallis entropy is non-logarithmic. After the introduction of Shannon entropy , the conditional Shannon entropy was derived and its properties became known. Also, for Tsallis entropy, the conditional entropy was introduced a...
The structural origin of enzyme adaptation to low temperature, allowing efficient catalysis of chemical reactions even near the freezing point of water, remains a fundamental puzzle in biocatalysis. A remarkable universal fingerprint shared by all cold-active enzymes is a reduction of the activation enthalpy accompanied by a more negative entropy, which alleviates the exponential decrease in ch...
Major evidence points towards a link between inflammation and type 2 diabetes, insulin resistance and diabetic complications, where monocytes are deeply involved. Entropy (information dimension) of pericellular membrane of monocytes was evaluated in diabetic patients and in control subjects. Monocytes were collected from normal healthy volunteers (n=6) and from type 2 diabetic patients (n=10). ...
an economic system is comprised of different primary flows that can be captured in macroeconomic models with complex network relations. theoretically and empirically in this system, weak substitution or complementarity of environmental materials, like energy and other production factors such as capital, is undeniable. this is an effective critique on neoclassical economics. in this paper, we vi...
Crystalline soybean trypsin inhibitor protein undergoes denaturation on heating which is reversed on cooling. In the range of temperature of 35 to 50 degrees C. a solution of the protein consists of a mixture of native and denatured forms in equilibrium with each other. The equilibrium is only slowly established and its final value at any temperature is the same whether a heated, denatured solu...
Abstract Glass transition is one of the unresolved critical issues in solid-state physics and materials science, during which a viscous liquid frozen into solid or structurally arrested state. On account uniform mechanism, calorimetric glass temperature ( T g ) always follows same trend as dynamical (or α -relaxation) determined by dynamic mechanical analysis (DMA). Here, we explored correlatio...
In this paper, we introduce a new entropy-like invariant, named Hausdorff metric entropy, for finitely generated semigroups acting on compact metric spaces from a set-valued view and study its properties. We establish the relation between Hausdorff metric entropy and topological entropy of a semigroup defined by Bis. Some examples with positive or zero Hausdorff metric entropy are given. Moreov...
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