Mass transfer in a protein A medium with silica matrix was analyzed this study. Using confocal laser scanning microscopy, we monitored the positional and temporal changes polyclonal human IgG during batch adsorption. simple theoretical model based on Fick’s law of diffusion Langmuir adsorption used to numerically approximate external intraparticle mass-transfer properties single particles. The ...

In this study, polyelectrolyte multilayers were fabricated on a polystyrene (PS) plate using a Layer-by-Layer (LbL) self-assembly technique. The resulting functional platform showed improved performance compared with conventional enzyme-linked immunosorbent assay (ELISA) systems. Poly(diallyldimethylammonium chloride) (PDDA) and poly(acrylic acid) (PAA) were used as cationic and anionic polyele...

Contamination of drinking water due to fluoride is a severe health hazard problem. Excess of fluoride (>1.5mg/l) in drinking water is harmful to the human health. Various treatment technologies for removing fluoride from groundwater have been investigated in the past. Present investigation aims to remove fluoride by activated alumina. Adsorption isotherm has been modeled by Langmuir equation an...

BACKGROUND A column sorption study was carried out using calcium alginate gel beads as adsorbent for the removal of boron from aqueous solutions. The breakthrough curve was obtained as a function of pH, initial concentration of boron, feed flow rate, adsorbent mass and column diameter. The breakthrough capacity values and adsorption percentage of calcium alginate gel for boron were...

Global environmental pollution challenges can be alleviated if proper disposal and conversion of wastes is promoted. An attempt of converting waste to wealth was made in this study by converting oil palm empty fruits bunch to activated carbon through chemical activation with potassium hydroxide which was used for adsorption of Rhodamine B dye from waste water. Fixed-bed column adsorption system...

The adsorption of benzene and C60 on graphene and boron nitride is studied using density functional theory with the van der Waals density functional (vdW-DF). By comparing these systems we can systematically investigate their adsorption nature and differences between the two functional versions vdW-DF1 and vdW-DF2. The bigger size of the C60 molecule makes it bind stronger to the surface than b...

Application of Granular Activated Carbon (GAC) in adsorption process has been studied for the advanced treatment of municipal and industrial wastewater. Because of entering poisonous compounds such as furfural, phenol and sulfides into the oily wastewater of Tehran refinery, biological aeration basins of wastewater treatment unit may not have the desired performance of COD reduction. In this st...

The kinetics in a fixed-bed adsorption system is explained using a mathematical model that takes into account of external and internal mass-transfer resistances with a nonideal plug flow behavior. The variation of fluid velocity along the column is an important aspect, which has not been accounted so far in these models. In the present study, a mathematical model is proposed for explaining the ...

We calculate the ion and composition distributions around colloid particles in an aqueous mixture, accounting for preferential adsorption, electrostatic interaction, selective solvation among ions and polar molecules, and composition-dependent ionization. On the colloid surface, we predict a precipitation transition induced by a strong preference of hydrophilic ions to water and a prewetting tr...