نتایج جستجو برای: aminated polymers
تعداد نتایج: 71343 فیلتر نتایج به سال:
This paper describes measurements of the dynamics of hot electron cooling in photoexcited gold nanoparticles (Au NPs) with diameters of ∼3.5 nm, and passivated with either a hexadecylamine or hexadecanethiolate adlayer, using ultrafast transient absorption spectroscopy. Fits of these dynamics with temperature-dependent Mie theory reveal that both the electronic heat capacity and the electron-ph...
A copper(I)-catalyzed, (diacetoxyiodo)benzene [PhI(OAc)2]-mediated ring-expansion/thiolactonization of a-oxo ketene dithioacetals was efficiently realized via azidation of the internal olefinic C@H bond with sodium azide under mild conditions. Sequential amination, ring-expansion rearrangement, and thiolactonization occurred to form aminated thiolactones in the presence of acetic anhydride as t...
A carbon nanotube transistor array was used to detect DNA hybridization. A new approach to ensure specific adsorption of DNA to the nanotubes was developed. The polymer poly (methylmethacrylate(0.6)-co-poly(ethyleneglycol)methacrylate(0.15)-co-N-succinimidyl methacrylate(0.25)) was synthesized and bonded noncovalently to the nanotube. Aminated single-strand DNA was then attached covalently to t...
تنها فرایند پلیمری که نانوذرات پلیمری تولید می کند، پلیمریزاسیون امولسیونی است. نانوذرات پلیمری آن قدر در زندگی بشر و پیشرفت فناوری اهمیت پیدا کرده اند که می توان گفت بدون آنها، و به طور کلی مواد پلیمری، پیشرفت امکان پذیر نیست. شبیه سازی فرآیند ها در علوم مهندسی بسیار مهم است، که در صورت شبیه سازی مناسب، هزینه های مصرفی قبل از ایجاد واحد در جهت انجام آزمایشات لازم، کاهش می یابد. یکی از نر...
Chemically functionalized carbon nanotubes (f-CNTs) have been used in proof-of-concept studies to alleviate debilitating neurological conditions. Previous in vivo observations in brain tissue have suggested that microglia - acting as resident macrophages of the brain - play a critical role in the internalization of f-CNTs and their partial in situ biodegradation following a stereotactic adminis...
There is evidence that nanoparticles (NP) can enter the bloodstream following deposition in the lungs, where they may interact with platelets. Polystyrene latex nanoparticles (PLNP) of the same size but with different surface charge-unmodified (umPLNP), aminated (aPLNP), and carboxylated (cPLNP)-were used as model NP to study interactions with human blood and platelets. Both the cPLNP and the a...
In this work, 3-nitro-1H-1,2,4-triazole (1) and 3,5-dinitro-1H-pyrazole (2) were C-aminated and N-aminated using different amination agents, yielding their respective C-amino and N-amino products. All compounds were fully characterized by NMR (1H, 13C, 15N), IR spectroscopy, differential scanning calorimetry (DSC). X-ray crystallographic measurements were performed and delivered insight into st...
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