In this work, hybrid atomistic-macroscale simulation is conducted to explore the crystallization and amorphization of Si surface in the situation of fast melting and solidification induced by ultrafast laser heating and heat conduction. Our work is focused on investigating the relationship between the amorphization threshold (Ec) and the laser pulse width (tg). An empirical correlation Ec 1⁄4 4...

We demonstrate n- and p-type field-effect transistors based on Si nanowires (SiNWs) implanted with P and B at fluences as high as 10(15) cm (-2). Contrary to what would happen in bulk Si for similar fluences, in SiNWs this only induces a limited amount of amorphization and structural disorder, as shown by electrical transport and Raman measurements. We demonstrate that a fully crystalline struc...

The flexibility window in zeolites was originally identified using geometric simulation as a hypothetical property of SiO2 systems. The existence of the flexibility window in hypothetical structures may help us to identify those we might be able to synthesize in the future. We have previously found that the flexibility window in silicates is connected to phase transitions under pressure, struct...

Phase transformations under high strain rates (dynamic compression) are examined in situ on ZrW2O8, a negative thermal expansion ternary ceramic displaying polymorphism. Amorphization, consistent with prior quasi-static measurements, was observed at peak pressure of 3.0 GPa dynamic conditions, which approximate those expected during fabrication. Evidence partial amorphization lower (1.8 GPa) th...

Raman spectra of cobalt hydroxide Co(OH)2 were recorded to 31 GPa using a diamond anvil cell. In contrast to a previous infrared ~IR! spectroscopic study, our Raman data show no sharp change in the O-H stretch peak width near 11 GPa, ruling out the possibility of abrupt hydrogen sublattice amorphization at this pressure. This is consistent with neutron diffraction data for Co(OD)2 to 16 GPa whi...

Previous high-pressure experiments have shown that pressure-transmitting fluids composed of small molecules can be forced inside the pores of metal organic framework materials, where they can cause phase transitions and amorphization and can even induce porosity in conventionally nonporous materials. Here we report a combined high-pressure diffraction and computational study of the structural r...

a r t i c l e i n f o The amorphization and graphitization of single-crystal diamond by ion implantation were explored using transmission electron microscopy (TEM). The effect of ion implantation and annealing on the microstructure was studied in (100) diamond substrates Si + implanted at 1 MeV. At a dose of 1 × 10 15 cm − 2, implants done at 77 K showed a damage layer that evolves into amorpho...