The enthalpy and volume changes, deltaH and deltaV, associated with the 266 nm laser-induced photoionization reactions of aqueous ferrocyanide and iodide ions, to yield the hydrated electron, e(-)aq, and oxidized products were determined by temperature-dependent time-resolved photoacoustics. The photoionization quantum yield as function of temperature (9-30 degrees C) was determined by laser fl...

The physicochemical properties of solute in solutions provide valuable information on solute –solvent, solute – solute and solvent – solvent interactions. The intermolecular forces between theliquids molecules and solvent molecules affect the viscosity of the solution. Information regardinginter and intra molecular interactions can be obtained from volumetric, and viscometric data in asolute so...

The long-grain, specialty rice cultivars, Bolivar, Cheniere, Dixiebelle, and L-205 are used for wet-pack canning. These cultivars have similar apparent amylose content but showed differences in canning, pasting, and gelatinization properties. Starch fine structures were analyzed to rationalize observed differences in functionality. Cheniere amylopectin had the lowest weight-average molar mass (...

Densities and excess molar volume of the binary and ternary mixtures formed by nbutylacetate+ 1-butanol + 1,2-butanediol were measured at (298.15, 303.15, and 308.15) K forthe liquid region and at ambient pressure (81.5) k Pa , for the whole composition range. Theexcess molar volumes,VmE and excess partial molar volume ViE ,were calculated fromexperimental densities.The excess molar volumes are...

effect of sucrose replacement with date syrup powder on physiochemical properties of sponge cake such as specific gravity, volume, apparent density, solid density, porosity, symmetry, moisture content, water activity, crust color and textural firmness was studied. batter specific gravity of the control sample was higher than that of other samples. sucrose replacement with 100% of date syrup pow...

The density (ρ) and ultrasonic velocity (U) for ternary mixture of dimethyl acetamide, isobutyl methyl ketone and diethyl ether at different frequencies (2MHZ, 4MHz, 6MHZ, 8MHZ) have been measured at 308K. These data have been used to compute adiabatic compressibility (Ks), intermolecular free length (Lf), acoustic Impedance (Z), molar volume (Vm), molar sound velocity(R), molar compressibility...