The effect of the type of polymer used to disperse Single-Walled Carbon Nanotubes (SWNTs) on the optical limiting performances of the resulting dispersions was studied. One conjugated polymer Poly(9,9-di-n-hexylfluorenyl-2,7-diyl) (PFO) possessing a flexible backbone, and two conjugated polymers Poly(2,5-dioctylphenylene1,4-ethynylene) (PPE), and Poly(9,9-dioctylfluorenyl-2,7-yleneethynylene) (...

Four polymer-supported benzotriazoles were prepared by linkage of 5-(hydroxymethyl)benzotriazole and benzotrizaole-5-carboxylic acid with Wang resin, Merrifield resin, and (monomethoxy)poly(ethylene glycol). The solid-phase and liquid-phase syntheses of tetrahydroquinolines were achieved by two-pair coupling reactions of aldehydes and aromatic amines using these polymer-supported benzotriazoles...

A composite gel composed of a water-soluble aromatic polyamide hydrogelator and the nanosheet Laponite®, a synthetic layered silicate, was produced and found to exhibit thixotropic behaviour. Whereas the composite gel contains the gelator at the same concentration as the molecular gel made by the gelator only, the composite gel becomes a softer thixotropic gel compared to the molecular gel made...

The main goal of this study was to prepare and characterize ion exchangers on nanofibrous polystyrene matrix. Starting nanofibers were sulfonated and crosslinked at the same time by sulfuric acid. Strongly acidic cation exchanger was obtained in such a way. Anion exchanger was prepared by reaction of ethylene diamine with sulfochlorides on nanofibers acquired from sulfogroups. The polymer matri...

The band structure and electronic properties in a series of vinylene-linked heterocyclic conducting polymers are investigated using density functional theory (DFT). In order to accurately calculate electronic band gaps, we utilize hybrid functionals with fully periodic boundary conditions to understand the effect of chemical functionalization on the electronic structure of these materials. The ...

The reactions of group 13 metal trichlorides with aromatic azides were examined by CW EPR and pulsed ENDOR spectroscopies. Complex EPR spectra were obtained from reactions of aluminium, gallium and indium trichlorides with phenyl azides containing a variety of substituents. Analysis of the spectra showed that 4-methoxy-, 3-methoxy- and 2-methoxyphenyl azides all gave 'dimer' radical cations [Ar...

A self-developed and newly re-designed chemical SAW sensor system composed of four polymer-coated differently modified nano-diamond-coated sensors was applied to measure aromatic compounds in gasoline a low-cost, fast, easy way. An additional short packed column at the inlet improve selectivity for various possible fuel applications. The allows direct sampling liquid fuels pre-separates differe...

Several synthetic strategies based on the use of substituted aromatic and hetero-aromatic thiols for the covalent binding of modifier compounds to PVC are described. A variety of aliphatic alcohols and amines are linked to the aromatic or heteroaromatic rings via highly active functionalities as the isocyanate, acidchloride, or chlorosulfonyl group, and the three chlorine atoms of trichlorotria...

Lignin is an energy-dense, heterogeneous polymer comprised of phenylpropanoid monomers used by plants for structure, water transport, and defense, and it is the second most abundant biopolymer on Earth after cellulose. In production of fuels and chemicals from biomass, lignin is typically underused as a feedstock and burned for process heat because its inherent heterogeneity and recalcitrance m...

The grafting of polymers onto a carbon black surface based on the trapping of polymer radicals by polycondensed aromatic rings of the surface was investigated. It was found that polymer radicals formed by the thermal decomposition of azo-polymer, peroxy-polymer and 2,2,6,6-tetramethylpiperidinyl-1-oxy-terminated polymer are successfully captured by a carbon black surface to give the correspondi...