نتایج جستجو برای: buchwald hartwig reaction

تعداد نتایج: 412816  

Journal: :Organic Letters 2021

Conjugation-extended carbazolophane donors, dicarbazolophanes (DCzp), were designed and synthesized using a multifold stepwise Pd-catalyzed Buchwald–Hartwig amination/ring cyclization process. Furthermore, elaboration of the DCzp core is possible with introduction pendant carbazole derivative groups. This provides way to tune optoelectronic properties thermally activated delayed fluorescence (T...

Journal: :Dalton transactions 2011
Ratanon Chotima Tim Dale Michael Green Thomas W Hey Claire L McMullin Adam Nunns A Guy Orpen Igor V Shishkov Duncan F Wass Richard L Wingad

Reaction of [Pd(PPh(3))(4)] with 1,1-dichloro-2,3-diarylcyclopropenes gives complexes of the type cis-[PdCl(2)(PPh(3))(C(3)(Ar)(2))] (Ar = Ph 5, Mes 6). Reaction of [Pd(dba)(2)] with 1,1-dichloro-2,3-diarylcyclopropenes in benzene gave the corresponding binuclear palladium complexes trans-[PdCl(2)(C(3)(Ar)(2))](2) (Ar = Ph 7, p-(OMe)C(6)H(4)8, p-(F)C(6)H(4)9). Alternatively, when the reactions ...

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