Ring-opening polymerization (ROP) of ethylene carbonate (EC) is associated with the emission of carbon dioxide during polymerization, which results in polymer chains containing ether linkages besides targeted carbonate linkages. In this study, ethylene carbonate is polymerized by ring-opening polymerization in the presence of sodium stannate trihydrate as a heterogeneous transesterification cat...

The reaction of TiCl3 ⋅ 3THF with perfluoropinacol (H2fpin), triethylamine and silver nitrite in acetonitrile yielded the formation first tris(perfluoropinacolato) complex a transition metal, (HNEt3)3[TiIV(fpin)3]NO2 (1). compound was fully characterized IR UV-vis spectroscopy as well elemental analysis single crystal X-ray diffraction. structure 1 is compared that known homoleptic titanium(IV)...