In this study, the novel surface ion-imprinted polymer (IIP) particles were prepared and applied as a electrode modifier in stripping voltammetric detection of lead(II) ion. A carbon paste electrode (CPE) modified with IIP nanoparticles and multi-walled carbon nanotubes (MWCNTs) was used for accumulation of toxic lead ions. Various factors that govern on electrochemical signals including carbon...

a carbon-paste electrode (cpe) chemically modified with the n-4,4'-azodianiline(ferrocenyl schiff base) complex and multi wall carbon nanotubes (adafcnte) was used as a highly sensitive electrochemical sensor for determination of trace amounts of atenolol. the oxidation peak potentials in cyclic voltammogram of adafcnte occurred around 550 mv vs ag/agcl (at ph 6.0) while this peak potentia...

In this work, for the first time, a new and effective bulk modified carbon paste electrode (CPE) was prepared by TiO2 nanoparticles and chitosan and then Ni2+ ions were incorporated to this electrode by immersion of the modified electrode in nickel chloride solution. The values of electron transfer coefficient, charge-transfer rate constant and electrode surface coverage f...

A montmorillonite from Wyoming-USA was used to prepare an organo-clay complex, named 2-thiazoline-2-thiol-hexadecyltrimethylammonium-clay (TZT-HDTA-clay), for the purpose of the selective adsorption of the heavy metals ions and possible use as a chemically modified carbon paste electrode (CMCPE). Adsorption isotherms of Hg2+, Pb2+, Cd2+, Cu2+, and Zn2+ from aqueous solutions as a function of th...

Carbon paste electrodes have been modified with some lipidsfor the sensitive and selective detection of the antidepressant (Desipramine). Voltammetric experimental conditions were optimized taking into account the importance of quantifying desipramine in the complex media and in the pharmaceutical formulations. The sensor(Lauric acid modified carbon paste electrode) responds to desipramine givi...

Manganese is an essential micronutrient for all organisms; however at high concentrations it has a toxic effect. Manganese toxicity is a serious constraint to crop cultivation since it is taken-up by plants and can easily be passed into the food chain again causing symptoms of Parkinson’s disease. A fully validated square-wave adsorptive cathodic stripping voltammetry method has been developed ...

a carbon paste electrode modified with cobalt (ii) phthalocyanine (copc) was used as a sensitive potentiometric sensor for determination of ascorbic acid in aqueous solutions. the potential response of the electrode is a linear function of ascorbic acid concentration over the range 5 10 to 10 m (?1- 1800 µg ml ) with a nernstian slope of 56 mv at ph 7. the limit of detection was 0.2 µg ml ascor...

a sodium dodecyl sulfate modified carbon paste electrode (sds/cpe) was developed in this work based on the surface modification method. the modified electrode was prepared by immersing sds/cpe in a nickel nitrate solution. this electrode showed a strong accumulation ability toward nickel ions. then modified electrode was conditioned by potential recycling in a potential range of 0.2–0.8 v (vs. ...