Nickel supported on SBA-15 doped with CeO2 catalysts (Ni-CeO2/SBA-15) was prepared, and used for steam reforming of toluene which was selected as a model compound of biomass gasification tar. A fixed-bed lab-scale set was designed and employed to evaluate the catalytic performances of the Ni-CeO2/SBA-15 catalysts. Experiments were performed to reveal the effects of several factors on the toluen...

Previous experimental studies have shown that addition of small amounts of oxygen to a hydrocarbon fuel stream can control coking in the anode, while relatively large amounts of oxygen are present in the fuel stream in single-chamber solid oxide fuel cells SOFCs . In order to rationally design an anode for such use, it is important to understand the coupled catalytic oxidation/ reforming chemis...

In this study, the modeling of hydrogen production process in microreactors by methanol-steam reforming reaction is investigated. The catalytic reaction of methanol-steam reforming producing hydrogen is simulated considering a 3D geometry for the microreactor. To calculate diffusion among species, mixture average correlations are compared to Stephan-Maxwell equations. The reactions occurring in...

A small-size gasification unit is improved through process optimization to simulate industrial United Gas Improvement Company gasification. It finds that the reaction temperature has important impacts on semicoke catalyzed methane gas mixture. The addition of water vapor can enhance the catalytic activity of reforming, which is due to the fact that addition of water vapor not only removes carbo...

The naphtha catalytic reforming process is evaluated by designing new composite nano-catalysts. Three catalysts were prepared for this process. first catalyst was molybdenum carbide with platinum over HY zeolite (Mo2C.Pt/HY zeolite), the second modified cerium nitrate (Mo2C.Pt/CeY and last bimetallic titanium a content of 1% 0.11% (Pt.Ti/HY zeolite). All tested several tests, mainly X-Ray Diffr...

We introduce a new method for performing and miniaturizing many types of heterogeneous catalysis involving nanoparticles. The method makes use of the plasmon resonance present in nanoscale metal catalysts to provide the necessary heat of reaction when illuminated with a low-power laser. We demonstrate our approach by reforming a flowing, liquid mixture of ethanol and water over gold nanoparticl...

In this paper, we address the conceptual design of the bioethanol process from switchgrass via gasification. A superstructure is postulated for optimizing energy use that embeds direct or indirect gasification, followed by steam reforming or partial oxidation. Next, the gas composition is adjusted with membrane-PSA or water gas shift. Membrane separation, absorption with ethanol-amines and PSA ...