Solutions of surfactant-polymer mixtures often exhibit different foaming properties, compared to the solutions of the individual components, due to the strong tendency for formation of polymer-surfactant complexes in the bulk and on the surface of the mixed solutions. A generally shared view in the literature is that electrostatic interactions govern the formation of these complexes, for exampl...

Cationic amphiphiles have received increasing attention as antimicrobials given their unique ability to disrupt bacteria cell membranes. While extensive research has demonstrated that amphiphiles' hydrophobic-to-charge ratio significantly modulates antibacterial activity, less work has focused on elucidating the specific impact of charge location on amphiphile bioactivity. In this study, two se...

A series of novel dissymmetric gemini cationics surfactants was synthesized by three-step reactions. The dissymmetric gemini surfactants contain a dodecanoic acid dimethylethylamine ester as the constant cationic part on one side of the hydroxypropyl center and a similar other cationic part, but with a different acid length (from octanoic to palmitic), on the other side. The critical micelle co...

The surface properties and mixed micellization behaviour of single gemini bis(hexadecyldimethylammonium) pentane dibromide (G5) surfactant, three conventional surfactants (Cationic cetyltrimethylammonium bromide (CTAB), anionic sodium dodecyl sulfate (SDS) and nonioinic Polyethylene glycol dodecyl ether (Brij35)) and their equimolar binary mixtures have been investigated by surface tension and ...

Gemini surfactants typically consist of two single-chain surfactants chemically linked by a spacer molecule. We report herein the results of fully atomistic molecular dynamics (MD) simulations of a series of Gemini surfactants: CsH2s-alpha,omega-bis(C12H25N+(CH3)2Cl-), at the air/water interface with s = 3, 4, 6, 12, 14, and 16, at values of the initial surface area per surfactant AS = 70 A2, 7...

Surfactant-based nanostructures are promising materials for designing novel colorimetric biosensors based on aggregation/disaggregation phenomena. In this work, a sensor the plasmonic shift of surfactant-capped gold nanoparticles via disaggregation mechanism was developed. To perform this, optimum SDS concentration firstly determined in order to form Au@16-s-16/SDS complex aggregates with well-...

A cationic gemini surfactant, dodecanediyl-1,12-bis(dodecyldiethylammonium bromide) (C12C12C12(Et)), in aqueous solutions with varying NaBr concentration was studied by dynamic light scattering (DLS). As a comparison, its single-chained counterpart, dodecyl triethylammonium bromide (DTEAB), was also investigated under the same conditions. Similar to the case of a polyelectrolyte, C12C12C12(Et) ...

Kinetics of the title reaction has been carried out by studying the reaction spectrophotometrically at 80 oC and pH 5.0 in presence of cationic gemini (alkanediyl-α, ωbis(dimethylhexadecylammonium bromide)) surfactants. The reaction followed first-order kinetics in [Zn(II)-Gly-Tyr]T complex and fractional-order kinetics in [ninhydrin]T. Typical rate constant (kΨ) increase and leveling-off regio...

The effect of addition of sodium anthranilate to 5 mM micellar solutions of gemini surfactant 1,4-bis(N-hexadecyl-N,N-dimethylammonium)butane dibromide is investigated by 1H NMR. The solubilization site of anthranilate anion near the micellar surface is inferred. In the micelles, the An- ions intercalate among the surfactant headgroups producing morphological changes.

the pollution of water environments is a challenging issue especially in developing countries. contamination of drinking water with heavy metals has been reported in many parts of the world. arsenic, chromium and lead are dangerous heavy metals and also common contaminants of drinking water. in this study, the capacity and performance of the surfactant-modified sabzevar natural nanozeolite (sms...