meysam yarie was born in 1987 in malayer, hamedan, iran. he received his b.sc. in applied chemistry (2010) from malek-ashtar university of technology and m.sc. in organic chemistry (2012) from kurdistan university under the supervision of dr. kamal amani. he is currently working towards his ph.d. under the supervision of professor mohammad ali zolfigol. his research interest is catalysis, inclu...

Although azides have been widely used in nitrene transfer reactions, in situ generation of N-H imines from azides for downstream transformations has rarely been explored. We report copper-mediated formation of N-unsubstituted aliphatic imines from easily available aliphatic azides using a customized phenanthroline-based ligand (L1*). Through trapping in situ-generated N-H imines, multisubstitut...

ehsan noroozizadeh was born in dezful/khoozestan, iran. he received his b.s. in pure chemistry (2011) and m.s. in organic chemistry (2013) from bu-ali sina university, iran. he is currently working towards his ph.d. under the supervision of professor mohammad ali zolfigol. his research interest is catalysis, including the application of homogeneous and heterogeneous catalysis in organic synthesis.

The synthesis, molecular and electronic structures, redox properties of pyrazine(diimine) (PzDI) metal dihalide complexes (DiPPPZDI)MX2 (DiPP = 2,6-diisopropylphenyl; M Mn, Fe, Co, Ni; X Cl, Br) are presented compared. reduced to (DiPPPZDI)MX monohalide complexes, the role ligand non-innocence in structure compounds is examined compared related pyridine(diimine) (PDI) compounds. were characteri...