Iron (III) oxides are ubiquitous in near-surface soils and sediments and interact strongly with dissolved phosphates via sorption, co-precipitation, mineral transformation and redox-cycling reactions. Iron oxide phases are thus, an important reservoir for dissolved phosphate, and phosphate bound to iron oxides may reflect dissolved phosphate sources as well as carry a history of the biogeochemi...

2014 The deuterium quadrupole splitting, 03BDQ, of C6D6 dissolved in a number of discotic liquid crystals has been measured over the temperature range of the mesophase stability. Three different types of mesophases were used : (i) Dho, which is a columnar hexatic phase with ordered molecular stacking; (ii) Drd, which is a rectangular biaxial columnar phase with disordered molecular stacking ; (...

Biogeochemistry of metals in aquatic sediments is strongly influenced by bioturbation. To determine the effects of biological transport on cadmium distribution in freshwater sediments, a bioturbation model is explored that describes the conveyor-belt feeding of tubificid oligochaetes. A stepwise modelling strategy was adopted to constrain the many parameters of the model: (i) the tubificid tran...

This discussion paper is/has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP if available. Abstract It is now accepted that one of the important pathways of Secondary Organic Aerosol (SOA) formation occurs through aqueous phase chemistry in the atmosphere. However , the liquid phase chemical mechanisms leading to ma...

during estuarine mixing of fresh water with saline water and due to the flocculation process, aportion of dissolved metals come into particulate phase, and the dissolved load decreases. this process plays an important role in self-purification of heavy metals in rivers. in this study, flocculation of cu, mn, ni, pb and zn during mixing of cheshme-kileh river water with caspian sea water has bee...

The application of Inconel 713C is very vast in different industries such as in automobiles, aircrafts, boilers and turbines. In this paper, Inconel 713C specimens were solutionized at 1000 and 1200 °C for 1 hours in order to study changes in phases and the structure of alloy to modify the γ' phase. The optical and the scanning electron microscopy were used to investigate the structure and the ...

Chlorinated solvents are the most prevalent organic contaminants found in ground water (Stroo et al. 2003), and in the dissolved phase they are typically mobile and recalcitrant, particularly trichloroethylene (TCE) and tetrachloroethylene (PCE). Schwille (1984, 1988) was the first to recognize that chlorinated solvent plumes (i.e., zones of dissolved phase contaminants) are caused by immobile ...