In this study, an  organic compound  inhibitor, namely N-benzyl-N-(4-chlorophenyl)-1H-tetrazole-5-amine (NBTA), was synthesized and the role of this inhibitor for corrosion protection of stainless steel (SS) exposed to 0.5 M H2SO4 was investigated using electrochemical, and quantum analysis. By taking advantage of potentiodynamic polarization, the inhibitory action of NBTA was found t...

This work presents the modelling of impulsional pH variations in microvolume related to water-based electrolysis and hydrogen peroxide electrochemical oxidation using an Electrochemical Field Effect Transistor (ElecFET) microdevice. This ElecFET device consists of a pH-Chemical FET (pH-ChemFET) with an integrated microelectrode around the dielectric gate area in order to trigger electrochemical...

Monitoring pluripotent stem cell behaviors (self-renewal and differentiation to specific lineages/phenotypes) is critical for a fundamental understanding of stem cell biology and their translational applications. In this study, a multi-modal stem cell monitoring system was developed to quantitatively characterize physico-electrochemical changes of the cells in real time, in relation to cellular...

An array of analytical methods including surface area determination by gas adsorption using the Brunauer, Emmett, Teller (BET) method, combustion analysis, XRD, ToF-SIMS, TEM and impedance spectroscopy has been used to investigate the interaction of gadolinia doped ceria (GDC) with hydrogen sulphide containing reducing atmospheres. It is shown that sulphur is incorporated into the GDC bulk and ...

Nanoporous gold (np-Au), because of its high surface area-to-volume ratio, excellent conductivity, chemical inertness, physical stability, biocompatibility, easily tunable pores, and plasmonic properties, has attracted much interested in the field of nanotechnology. It has promising applications in the fields of catalysis, bio/chemical sensing, drug delivery, biomolecules separation and purific...

Electrochemical current and potential transients were measured during anodic oxidation of aluminum, on time scales of 0.1–100 ms after anodizing began. Aluminum foil samples were prepared by surface treatments yielding oxide films of thickness 5 nm or smaller. A mathematical model was developed for the transients based on steady-state and transient conduction phenomena established for much thic...

Complex interfacial phenomena and phase transformations that govern the operation of Li-ion batteries require detailed nanoscale 3D structural and compositional characterization that can be directly related to their capacity and electrical transport properties. For this purpose, we have designed model miniature all solid-state radial heterostructure Li-ion batteries composed of LiCoO2 cathode, ...

SOFCs have the potential to meet the critical energy needs of our modern civilization and minimize the adverse environmental impacts from excessive energy consumption. They are highly efficient, clean and can run on a variety of fuel gases. However, wide adoption of SOFCs is currently hindered by cell durability, manufacturing cost, and lack of fundamental understanding on electrochemical perfo...

An improved PEMFC model is developed. The improvement of the model includes modification for electrochemical reaction and mass transfer limitation at cathode and anode side. Global sensitivity analysis is used for evaluating the sensitivity of the model in parameter estimation. The simulation results reveal that estimated mass transfer coefficients depend on current density. The comparison show...

HILE THE L o c a l H i s t o r y Col lec t ion and the U n i v e r s i t y A r c h i v e s a r e housed in the s a m e r o o m s and a d m i n i s t e r e d by the s a m e staff in the U n i v e r s i t y of R o c h e s t e r L i b r a r y , each h a s i ts o w n ident i ty , its dist inc t h i s to ry and its s e p a r a t e p u r p o s e s and goals . T h e re l a t ionsh ip of the t w o col ...