regioselective synthesis of highly functionalized pyranopyrazoles was achieved in excellent yield from phenyl pyrazolone, substituted aromatic aldehyde with nitroketene-n,s-acetal in the presence of indium trichloride as a versatile catalyst under reflux condition in ethanol-water mixture. all reactions preceeded within a short period of time with excellent purity. all of the synthesized compou...

an efficient and environmentally benign   method for the synthesis of aryl iodides have been developed by diazotization of aromatic amines with nano2 and nanosilica periodic acid (nano-spia) as a green catalyst via grinding followed by a sandmeyer iodination by ki under solvent-free conditions at room temperature. the ensuing aryl diazonium salts supported on nano-spia were sufficiently stable ...

In this work, the SBA-15-supported dithizone-copper(I) [SBA-15-dtz–Cu(I)] complex as a new heterogeneous catalyst is prepared for the first time. The catalyst prepared is characterized by the FT-IR spectroscopy, SEM, and ICP techniques. This reusable heterogeneous catalyst can be used in the click reactions for the green and facile synthesis of 1,4-disubstituted 1,2,3-triazolesvia a on...

An efficient and eco-friendly method for the one-pot synthesis of 14-aryl-14H-dibenzo [a,i]xanthene-8,13-dione derivatives has been developed in the presence of Fe3O4@SiO2 core-shell nanoparticles. The multi-component reactions of 2-hydroxy-1,4-naphthoquinone, β-naphthol and aldehydes were efficiently catalyzed using novel nano-scale materials under reflux conditions. The present method offers ...

An efficient and eco-friendly method for the one-pot synthesis of 14-aryl-14H-dibenzo [a,i]xanthene-8,13-dione derivatives has been developed in the presence of Fe3O4@SiO2 core-shell nanoparticles. The multi-component reactions of 2-hydroxy-1,4-naphthoquinone, β-naphthol and aldehydes were efficiently catalyzed using novel nano-scale materials under reflux conditions. The present method offers ...

We discuss how to implement an " environmentally friendly " renormalization in the context of finite temperature field theory. Environmentally friendly renormalization provides a method for interpolating between the different effective field theories which characterize different asymptotic regimes. We give explicit two loop Padé resummed results for λφ 4 theory for T > T c. We examine the impli...

tetra-n-butyl ammonium hydroxide was used as a catalyst for one-pot, three component condensation reactions consisting of aromatic aldehydes, malononitrile and barbituric acid in ethanol:water solvent system at 60oc. current method has major advantages like mild reaction conditions with simple operation, high yields, by using a less toxic and lower costlier catalyst.in conclusion, we have explo...