epoxy – polysulfide copolymers without or with low amounts of epoxy in their structure have poor mechanical properties in oxidative curing system.to strengthen the mechanical properties of polysulfide elastomer inclusion of epoxy resin (epon828) as hard segment was studied. ft-ir spectroscopy and rheometry were used to verify the formation of epoxy-polysulfide copolymer.  results obtained from ...

A direct comparison of surface loading, interface shear strength, and interface hydrolytic stability was made between a phosphonate and two siloxane monolayers formed on the native oxide surface of Ti-6Al-4V. Surface loading for the phosphonate was ca. four times greater (on a nanomole/area basis) than for the siloxanes; mechanical strengths per surface-bound molecule were comparable, but the h...

We introduce a siloxane chain-based hydrophobizer that exhibits superior thermal and chemical stability compared to the conventional hydrophobizing silane agent under conditions of over 300 °C and pH 2-13. To demonstrate the capability of the siloxane chain-based hydrophobizer to serve as a highly robust chemical surface modifier, we present two applications: the formation of fine metal nanopar...

In a novel application, infrared spectroscopic ellipsometry is used to provide clear evidence for the formation of a covalent bond at a polymer/polymer interface. Specifically, there is evidence for the formation of a Si-O-C bond resulting from a reaction between the silyl (SiH) group of a poly(hydrogen methyl siloxane) crosslinker used in poly(dimethyl siloxane) and the carboxylic acid group o...

The creep behavior of basalt fiber reinforced epoxy (BFRE) and glass fiber reinforced epoxy (GFRE) composites was studied through tensile testing at high temperature. To study the effect of reinforcing epoxy, the micro glass powder (MGP) was added at various volume percentage into the epoxy resin in BFRE composites. The initial strain for all the specimens were evaluated and compared with each ...

In order to enhance the compatibilization and interfacial adhesion between epoxy and liquid carboxyl-terminated butadiene acrylonitrile (CTBN) rubber, an initiator was introduced into the mixture and heated to initiate the cross-linking reaction of CTBN. After the addition of curing agents, the CTBN/epoxy blends with a localized interpenetrating network structure were prepared. The mechanical p...

Branched Siloxane Brushes In article number 2301561, King Lun Yeung and co-workers develop a flexible hierarchically branched siloxane brushes by repeated grafting of on TiO2 nanorods. The facilitates water nucleation, while the structure promotes efficient droplet jumping. as-prepared surface displays significant improvement in harvesting at both high low humidity conditions, making it suitabl...