Acetylene cyclotrimerization catalyzed by palladium has been shown to proceed via the initial rapid formation of a C 4 H 4 species. This can either react with adsorbed acetylene to form benzene or alternatively, as has been recently suggested, it can dimerize forming cyclooctatetraene which decomposes to yield benzene. Trimerization is sufficiently fast that reaction is desorption rather than s...

Acetylene fermentation is a rare metabolism that was previously reported as being unique to Pelobacter acetylenicus Here, we report the genome sequence of Pelobacter sp. strain SFB93, an acetylene-fermenting bacterium isolated from sediments collected in San Francisco Bay, CA.

The growth mechanism of hydrocarbons in ionizing environments, such as the interstellar medium (ISM), and some combustion conditions remains incompletely understood. Ab initio molecular dynamics (AIMD) simulations and molecular beam vacuum-UV (VUV) photoionization mass spectrometry experiments were performed to understand the ion-molecule growth mechanism of small acetylene clusters (up to hexa...

Nanosized CuO-CeO2, CuO-Fe2O3, CuO-CeO2-Al2O3 and CuO-Fe2O3-CeO2-Al2O3 were prepared by co-precipitation and wet impregnation techniques and were used for Catalytic decomposition of acetylene to produce carbon nanotubes (CNTs). Weight gain technique was used to follow up the catalytic reactions. The results revealed that catalyst chemical composition, catalytic temperature, acetylene flow rate ...

We synthesised aryl acetylene derivatives as versatile probes for labelling of oligonucleotides. RNA oligomers bearing an aryl acetylene molecule rapidly reacted with benzylazide derivatives under ligand-free click reaction conditions.

Recently, it has been demonstrated that intermetallic compounds composed of Pd and Ga or Co and Al provide excellent selectivity for the hydrogenation of acetylene to ethylene. Motivated by experimental works on GaPd catalysts, we have performed a detailed ab initio study of acetylene hydrogenation by the pseudo 5-fold (120) surface of the isostructural and isoelectronic AlPd compound crystalli...

The mechanism of C2 formation in methane conversion using plasma discharge has been studied by researchers around the world with ambiguous conclusions. Motivated by this challenge, this paper discusses the pathway of acetylene formation based on experimental results using deuterium isotope. Methane was fed with deuterium with a ratio of 1 to 5. Ethane and acetylene were also fed with deuterium ...

This paper demonstrates an acetylene gas sensor based on an Ag-decorated tin dioxide/reduced graphene oxide (Ag-SnO₂/rGO) nanocomposite film, prepared by layer-by-layer (LbL) self-assembly technology. The as-prepared Ag-SnO₂/rGO nanocomposite was characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and Raman spectrum. The acetylene...