Fe2+ ion-selective membrane sensor has been fabricated from polyvinyl chloride (PVC) matrixmembrane containing neutral carrier tetra phenyl porphyrin (TPP) ionophore. The addition ofsodium tetraphenylborate (NaTPB) and the plasticizer DBP has been found to substantiallyimprove the performance of the sensor. The best performance was obtained with the sensor havinga membrane of composition of TPP...

Single spinel phases of Mn0.5Ni0.1Zn0.4Nd x Fe2- x O4 ferrite samples (x = 0.0, 0.01, 0.02, 0.05, 0.075, and 0.1) have been prepared by ceramic method and the composition dependence of the physical and magnetic properties has been investigated. SEM micrographs and EDX analysis revealed that there is no considerable effect for the Nd(3+) ion substitution on the average grain size or porosity, wh...

iron reducing bacteria (irb) are one of the most applicable microorganisms in various industrial and environmental activities. these bacteria play a main role in the natural iron transformation. they act in a reverse metabolic pathway in contrast to iron oxidizing bacteria. in the anaerobic conditions irb are capable to use ferric ion as the final electron acceptor and reduce fe3+ to fe2+. what...

Symmetric batteries, in which the same active material is used for positive and negative electrode, simplifying manufacture process reducing fabrication cost, have attracted extensive interest large-scale stationary energy storage. In this paper, we propose a symmetric battery based on titanium hexacyanoferrate (TiHCF) with two well-separated redox peaks of Fe3+/Fe2+ Ti4+/Ti3+ tested it aqueous...

The one-step synthesis of three imine boronic esters functionalized with pyridyl groups is described (1a-1c). presence or absence a methyl group affects the whole conformation, being bent “L” linear as determined by X-ray crystal diffraction. C–H⋯O, C–H⋯N, C–H⋯F and C–H … π hydrogen bond interactions support 2D supramolecular arrangements. Ligands were tested metal ion (M2+) sensors in solution...

in this paper, grafting of acrylic acid monomer on gum tragacanth was performed. variable of experiment included concentration of initiators and monomer, time, and temperature. grafting efficiency was measured in the term of percentage of grafting (%g) and percentage of grafting efficiency (%e). effectiveness of grafted gum in ferrous ion removal at different condition was assessed. according t...

The oxide glass-based anodes for lithium-ion Batteries (LiBs) still suffer from two critical drawbacks, that is, low reversible capacity and electrical conductivity. Here, we report a new way to overcome the drawbacks. Specifically, chose 50Fe2O3–50P2O5 (50Fe50P) glass as anode material LiBs, then thermally treat it at 1118 K (Tg+345 K) 0.5 h under reducing atmosphere (5 mol% H2+95 Ar). thermal...

Viable biomass production is a key determinant of suitability of antagonistic yeasts as potential biocontrol agents. This study investigated the effects of three metal ions (magnesium, ferrous, and zinc) on biomass production and viability of the antagonistic yeast, Candida diversa. Using response surface methodology to optimize medium components, a maximum biomass was obtained, when the collec...

The ability of superoxide anion (O2-) from stimulated human neutrophils (PMNs) to release ferrous iron (Fe2+) from transferrin was assessed. At pH 7.4, unstimulated PMNs released minimal amounts of O2- and failed to facilitate the release of Fe2+ from holosaturated transferrin. In contrast, incubation of phorbol myristate acetate (PMA)-stimulated PMNs with holosaturated transferrin at pH 7.4 en...